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The reaction of 2-aminomethylphenols and their copper(II) complexes with esters of phosphorus acids

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

2-Alkyl- and 2-dialkylaminomethylphenols (AMP) with different hydrophobic substituents at the nitrogen atom and their copper(II) complexes (CAMP) react with the esters of phosphorus acids in aqueous solutions of ethanol in two stages: phosphorylated AMP (PAMP) are formed at the first stage and then hydrolyzed to the corresponding acids. The reactivity of AMP and PAMP significantly decreases when the hydrophobicity and steric hindrances of substituents at the nitrogen atom increase. An inverse dependence was found for CAMP.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    I. S. Ryzhkina, L. A. Kudryavtseva, K. M. Enikeev & V. I. Morozov

  2. Kazan State University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    G. A. Boos & Yu. I. Sal'nikov

Authors
  1. I. S. Ryzhkina
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  2. L. A. Kudryavtseva
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  3. K. M. Enikeev
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  4. V. I. Morozov
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  5. G. A. Boos
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  6. Yu. I. Sal'nikov
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1355–1360, August, 2000.

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Ryzhkina, I.S., Kudryavtseva, L.A., Enikeev, K.M. et al. The reaction of 2-aminomethylphenols and their copper(II) complexes with esters of phosphorus acids. Russ Chem Bull 49, 1349–1354 (2000). https://doi.org/10.1007/BF02495075

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  • DOI: https://doi.org/10.1007/BF02495075

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