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Synthesis and structures of nickel(II) trimethylacetate dimers with coordinated diamines

  • Organometallic Chemistry
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Abstract

Thermal decomposition of the tetranuclear nickel(II) complex Ni4lη2-o-(NH2)(NHPh)C6H4|2(MeCN)2(μ-OOCCMe3)4(η2-OOCCMe3)2 (I) under an inert atmosphere (o-xylene, 140 °C) was investigated. Under these conditions, the asymmetric binuclear complex Ni|η2-o-(NH2)(NHPh)C6H4‖(η1-o-(NH2))(NHPh)C6H4|(η2,η-O,O-OOCCMe3)(η2-OOCCMe3) (2) was formed at the first stage. Complex2 was converted into the symmetric dimer Ni|η1-o-(NH2)(NHPh)C6H4|(μ-OOCCMe3)4 (3) upon recrystallization from benzene. The structures of complexes2 and3 were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    A. A. Sidorov, I. G. Fomina, A. E. Malkov, A. V. Reshetnikov, G. G. Aleksandrov, V. M. Novotortsev, S. E. Nefedov & I. L. Eremenko

Authors
  1. A. A. Sidorov
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  2. I. G. Fomina
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  3. A. E. Malkov
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  4. A. V. Reshetnikov
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  5. G. G. Aleksandrov
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  6. V. M. Novotortsev
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  7. S. E. Nefedov
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  8. I. L. Eremenko
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Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1915–1918, November, 2000.

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Sidorov, A.A., Fomina, I.G., Malkov, A.E. et al. Synthesis and structures of nickel(II) trimethylacetate dimers with coordinated diamines. Russ Chem Bull 49, 1887–1890 (2000). https://doi.org/10.1007/BF02494929

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  • DOI: https://doi.org/10.1007/BF02494929

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