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Synthesis and crystal structure of a supramolecular adduct of the cubane cluster [CIPdMo3Se4(H2O)7Cl2]+ with macrocyclic cavitand cucurbituril

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A new heterometallic selenide-bridged 60-electron complex containing the cubane cluster fragment [M03(μ3-Se)4Pd]4τ was prepared by heating a solution of [Mo3Se4(H2O)9]Cl4 and palladium black in 2M HCl. The cluster complex was isolated from aqueous solutions as a hydrolytically stable supramolecular adduct with macrocyclic cavitand cucurbituril. The molecular and crystal structure of {[ClPdMo3Se4(H2O)7Cl2](C36H36N24O12)Cl}·7H2O were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    M. N. Sokolov, D. N. Dybtsev, A. V. Virovets & V. P. Fedin

  2. Lehrstuhl für Anorganische Chemie, Universität des Saarlandes, D-66041, Saarbruecken, Germany

    K. Hegetschweiler

Authors
  1. M. N. Sokolov
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  2. D. N. Dybtsev
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  3. A. V. Virovets
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  4. K. Hegetschweiler
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  5. V. P. Fedin
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Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1905–1909, November, 2000.

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Sokolov, M.N., Dybtsev, D.N., Virovets, A.V. et al. Synthesis and crystal structure of a supramolecular adduct of the cubane cluster [CIPdMo3Se4(H2O)7Cl2]+ with macrocyclic cavitand cucurbituril. Russ Chem Bull 49, 1877–1881 (2000). https://doi.org/10.1007/BF02494927

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  • DOI: https://doi.org/10.1007/BF02494927

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