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Oxidation of aliphatic alcohols with the lead tetraacetate—metal halide system under mechanical activation

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The mechanochemical oxidation ofn-pentanol,n-hexanol, andn-octanol with the Pb(OAc)4-MHal system (M=Li, K; Hal=Cl, Br) in the absence of a solvent affords esters. and secondary alcohols with the composition C8H17OH and C9H19OH give ketones.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Rissian Federation

    N. I. Kapustina & G. I. Nikishin

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. D. Makhaev & A. P. Borisov

Authors
  1. N. I. Kapustina
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  2. V. D. Makhaev
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  3. A. P. Borisov
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  4. G. I. Nikishin
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Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1870–1873, November, 2000.

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Kapustina, N.I., Makhaev, V.D., Borisov, A.P. et al. Oxidation of aliphatic alcohols with the lead tetraacetate—metal halide system under mechanical activation. Russ Chem Bull 49, 1842–1845 (2000). https://doi.org/10.1007/BF02494921

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  • DOI: https://doi.org/10.1007/BF02494921

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