Skip to main content
SpringerLink
Log in

Chemical dynamics of ≡SiOC.O radicals grafted on the activated silica surface

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The chemical dynamics of≡SiOC.O radicals grafted on the silica surface was studied in the 77–290 K temperature interval. The rotation diffusion coefficients and characteristic times of rotational mobility of the radicals were estimated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. G. Mingalyov, A. Y. Fadeev, S. M. Staroverov, G. V. Lisichkin, and E. V. Lunina,J. Chromatogr., 1993,646, 267.

    Article  CAS  Google Scholar 

  2. V. I. Pergushov and A. L. Buchachenko,Izv. Akad. Nauk. Ser. Khim., 1998, 613 [Russ. Chem. Bull., 1998,47, 592 (Engl. Transl.)].

  3. V. I. Pergushov, E. G. Evtikhieva, and D. A. Tyurin,Izy. Akad. Nauk, Ser. Khim., 1992, 2092 [Russ. Chem. Bull., 1999,48, 2069 (Engl. Transl.)].

  4. N. Yu. Osokina, Yu. V. Razskazovskii, V. I. Pergushov and M. Ya. Mel'nikov,Zh. Fiz. Khim., 1995,69, 1858 [Russ. J. Phys. Chem., 1995,69, No. 10 (Engl. Transl.)].

    CAS  Google Scholar 

  5. V. A. Radtsig,Kinet. Katal., 1979,20, 448 [Kinet. Catal., 1979,20, No. 2 (Engl. Transl.)].

    CAS  Google Scholar 

  6. V. A. Gritsenko, A. A. Milov, and H. Wong,Modern Applications of EPR/ESR from Biophysics to Materials Science. Proc. of the First Asia-Pacific EPR/ESR Symposium, Hong Kong, 20–24 January 1997 Ed. C. Z. Rudowicz, Springer, 1997, p. 613.

  7. V. A. Radtsig and A. V. Bystrikov,Kinet. Katal., 1978,19, 713 [Kinet. Catal., 1978,19, No. 3 (Engl. Transl.)].

    CAS  Google Scholar 

  8. V. A. Radtsig,Kinet. Katal., 1996,37, 310 [Kinet. Catal., 1996,37, No. 2 (Engl. Transl.)]

    Google Scholar 

  9. J. R. Durig, M. A. Sens, F. Milani-nejad, E. J. Stampf, and J. D. Odom,J. Phys. Chem., 1978,82, 1836

    Article  CAS  Google Scholar 

  10. H. S. Gutowsky and C. H. Holm,J. Chem. Phys., 1956,25, 1228.

    Article  CAS  Google Scholar 

  11. D. J. Schneider and J. H. Freed,Biological Magnetic Resonance. Ch. 1,8, Eds. L. Berliner and J. Reuben, Plenum Press, New York, 1989.

    Google Scholar 

  12. A. Kh. Vorobiev, V. S. Gurman, and T. A. Klimenko,Phys. Chem. Chem. Phys., 2000,2, 379.

    Article  CAS  Google Scholar 

  13. A. Kh. Vorob'ev V. S. Gurman, and T. A. Klimenko,Izy. Akad. Nauk. Ser. Khim., 2000, 1065 [Russ. Chem. Bull. Int. Ed. Engl., 2000,49, 1059].

  14. M. G. Voronkov, V. P. Mileshkevich, and Yu. A. Yuzhelevskii,Siloksanovaya svyaz [Siloxame Bond], Nauka, Novosibirsk, 1976, 410 pp. (in Russian).

    Google Scholar 

  15. C. D. LeCroix, R. F. Curl, P. M. McKinney, and R. J. Myers,J. Mol. Spectrosc., 1974,53, 250.

    Article  CAS  Google Scholar 

  16. B. Csacvary, Zs. Wagner, P. Gomory, I. Hargittai, B. Rozsondai, and F. C. Mijlhoff,Acta Chim. Acad. Sci. Hung., 1976,90, 149.

    Google Scholar 

  17. J. D. Odom, E. J. Stampf, Y. S. Li, and J. R. Durig,J. Mol. Struct., 1978,49, 1.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonsov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    V. I. Pergushov

Authors
  1. V. I. Pergushov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1862–1865, November, 2000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pergushov, V.I. Chemical dynamics of ≡SiOC.O radicals grafted on the activated silica surface. Russ Chem Bull 49, 1834–1837 (2000). https://doi.org/10.1007/BF02494919

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02494919

Keywords

Search

Navigation