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P,S-Ligands. Complexes ofP,P,P′,P′-tetraphenylethylenediphosphine monosulfide with PdCl2

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

1:1 and 1:2 complexes of Ph2P(CH2)2P(S)Ph2 with PdCl2 were synthesized. Their structures were established by31P NMR and IR spectroscopy and X-ray diffraction analysis. In the crystals, the 1:1 complex has a chelate structure. In CH2Cl2, this complex partially dissociates at the Pd­.S=P bond. According to the X-ray diffraction data, only the PIII atoms the cationic chelate complex [Pd(Ph2P(CH2)2P(S)Ph2)2]2+ 2NO3 −.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    E. I. Matrosov, Z. A. Starikova, D. I. Labanov, I. M. Aladzheva, O. V. Bykhovskaya & T. A. Mastryukova

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  1. E. I. Matrosov
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  2. Z. A. Starikova
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  3. D. I. Labanov
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  4. I. M. Aladzheva
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  5. O. V. Bykhovskaya
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  6. T. A. Mastryukova
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1122–1127, June, 2000.

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Matrosov, E.I., Starikova, Z.A., Labanov, D.I. et al. P,S-Ligands. Complexes ofP,P,P′,P′-tetraphenylethylenediphosphine monosulfide with PdCl2 . Russ Chem Bull 49, 1116–1121 (2000). https://doi.org/10.1007/BF02494907

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  • DOI: https://doi.org/10.1007/BF02494907

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