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Ruthenium phosphine complexes as catalysts of alternating copolymerization of ethylene and carbon monoxide

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The properties of the ruthenium (II) phosphine complexes [Ru(dppe)2(OTs)2] and [Ru{PhP(CH2CH2CH2PPh2)2}(OTs)2] as catalysts of alternating copolymerization of ethylene and carbon monoxide were studied. The catalytic activity of these complexes in the absence of cocatalysis is low, but it is substantially increased in the presence of trifluoroacetic acid or 1,4-benzoquinone. These compounds are the first ruthenium complexes which catalyze copolymerization of ethylene and CO.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    O. V. Gusev, A. M. Kal'sin, T. A. Peganova & P. V. Petrovskii

  2. Institute of Problems of Chemical Physics, 142432, Chernogolovka, Moscow Region, Russian Federation

    G. P. Belov & E. V. Novikova

Authors
  1. O. V. Gusev
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  2. A. M. Kal'sin
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  3. T. A. Peganova
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  4. P. V. Petrovskii
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  5. G. P. Belov
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  6. E. V. Novikova
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Translated fromAkademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1119–1121, June, 2000.

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Gusev, O.V., Kal'sin, A.M., Peganova, T.A. et al. Ruthenium phosphine complexes as catalysts of alternating copolymerization of ethylene and carbon monoxide. Russ Chem Bull 49, 1113–1115 (2000). https://doi.org/10.1007/BF02494906

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  • DOI: https://doi.org/10.1007/BF02494906

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