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The structure of benzoyldimedone from X-ray diffraction analysis

  • Physical Chemistry
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Abstract

The structure of benzoyldimedone was established by X-ray diffraction analysis. The only tautomer was found. In this tautomer, the enol proton is covalently bound to the oxygen atom that is remote from the phenyl group. The role of steric and electronic factors in stabilization of the enol structure is analyzed. The geometric characteristics of the ring formed through an intramolecular hydrogen bond are discussed.

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Authors and Affiliations

  1. Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus, 5/2 ul. Zhodinskaya, 220141, Minsk, Belarus

    E. V. Borisov, A. I. Verenich, A. A. Govorova & T. S. Khlebnikova

  2. Institute of Physicochemical Problems, Belarussian State University, 14 ul. Leningradskaya, 220080, Minsk, Belarus

    A. S. Lyakhov

Authors
  1. E. V. Borisov
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  2. A. I. Verenich
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  3. A. A. Govorova
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  4. A. S. Lyakhov
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  5. T. S. Khlebnikova
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1074–1076, June, 2000.

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Borisov, E.V., Verenich, A.I., Govorova, A.A. et al. The structure of benzoyldimedone from X-ray diffraction analysis. Russ Chem Bull 49, 1068–1070 (2000). https://doi.org/10.1007/BF02494895

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  • DOI: https://doi.org/10.1007/BF02494895

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