Abstract
Analysis of a binary equilibrium in a distinct micropore showed that the noouniformity of the adsorption field results in a negative deviation of the adsorption solution from ideal behavior. This deviation is due to a decrease in the entropy and internal energy caused by rearrangement of adsorbed molecules. Different interactions between identical and different molecules in distinct micropores also result in a negative deviation from ideal behavior. A criterion was formulated that allows one to elucidate how the deviation from ideality depends on the nonuniformity of the adsorption space and the character of the interaction between molecules in a micropore.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No.6, pp. 1011–1017, June, 2000.
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Ustinov, E.A., Polyakov, N.S. Nonideality of binary mixtures in the adsorbent micropores. Russ Chem Bull 49, 1006–1011 (2000). https://doi.org/10.1007/BF02494884
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DOI: https://doi.org/10.1007/BF02494884