Abstract
An equation relating the rate constants of a bimolecular activation-controlled redox reaction to the parameters directly determined from the electronic absorption spectra was obtained in the framework of the Marcus-Hush theory. Applicability of the equation for the prediction of redox reaction rate constants was shown.
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Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No.6, pp. 1007–1010, June, 2000.
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Kotov, V.Y. Calculation of activation-controlled reaction rate constants from parameters of electronic absorption spectra of ion pairs. Russ Chem Bull 49, 1002–1005 (2000). https://doi.org/10.1007/BF02494883
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DOI: https://doi.org/10.1007/BF02494883