Russian Chemical Bulletin

, Volume 48, Issue 11, pp 2077–2079 | Cite as

Sulfur ylides

9. Resonance electron capture by molecules of keto-stabilized sulfur ylides containing a phthalimide fragment
  • V. K. Mavrodiev
  • I. I. Furlei
  • S. N. Lakeev
  • F. Z. Galin
  • G. A. Tolstikov
Physical Chemistry

Abstract

The mass spectra of negative ions of keto-stabilized sulfur and phosphorus ylides (obtained from amino acids) and products of their thermal conversion are studied. The most characteristic peaks in the mass spectra of ylides belong to negative molecular ions and to [M−H] ions. Peaks of fragment ions in the mass spectra of ylides and products of their thermal conversion coincide both in mass numbers and resonance energies.

Key words

mass spectrometry of negative ions resonance electron capture keto-stabilized sulfur and phosphorus ylides thermal conversion 

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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • V. K. Mavrodiev
    • 1
  • I. I. Furlei
    • 1
  • S. N. Lakeev
    • 1
  • F. Z. Galin
    • 1
  • G. A. Tolstikov
    • 1
  1. 1.Institute of Organic ChemistryUfa Scientific Center of the Russian Academy of SciencesUfaRussian Federation

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