Abstract
Transformations of HVinSiCl2, HVinSi(Me)Cl, HVinSi(Me)Ph, and HVinSi(Me)NEt2 in the presence of Pt catalyst were studied. In dilute solutions, the reaction gave a mixture of structural and stereoisomers of five- and six-membered disilacyclanes, resulting from intramolecular cyclization of the initially formed linear dimer. In the case of methyl(phenyl)disilacyclane, the structural isomers were separated andtrans-1,4-dimethyl-1,4-diphenyl-1,4-disilacyclohexane was isolated. The reaction of this product with HCl in the presence of AlCl3 followed by hydrolysis resulted in the synthesis oftrans-1,4-dichloro- andtrans-1,4-dihydroxy-1,4-dimethyl-1,4-disilacyclohexanes. The structures of the structural and stereoisomers synthesized were confirmed by1H,13C, and29Si NMR and IR spectroscopies and mass spectrometry.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1734–1738, September, 1999.
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Volkova, L.M., Petrova, I.M., Chizhova, N.V. et al. Synthesis of difunctional 1,4-dimethyl-1,4-disilacyclohexanes. Russ Chem Bull 48, 1712–1716 (1999). https://doi.org/10.1007/BF02494818
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DOI: https://doi.org/10.1007/BF02494818