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Electrochemical synthesis and properties of δ-fluoroacyl and δ-perfluoroalkyl transition metal complexes

  • Organometallic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The electrochemical synthesis of δ-fluoroacyl complexes [M]-δ-CORf(M=C5H5(CO)3W or (CO)5Mn; Rf=CF3 or C4F9) was performed according to two procedures: (1) the preliminary electrochemical synthesis of [M]− from [M]2 followed by reaction with a fluorine-containing compound and (2) the electrochemical synthesis of [M]− in the presence of a fluorine-containing compound. Trifluoroacetic anhydride was demonstrated to be the best acylating agent in these reactions. The electrochemical properties of the resulting complexes were studied.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    L. I. Denisovich, M. G. Peterleitner, A. A. Stepanov & S. M. Peregudova

Authors
  1. L. I. Denisovich
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  2. M. G. Peterleitner
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  3. A. A. Stepanov
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  4. S. M. Peregudova
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 373–375, February, 2000.

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Denisovich, L.I., Peterleitner, M.G., Stepanov, A.A. et al. Electrochemical synthesis and properties of δ-fluoroacyl and δ-perfluoroalkyl transition metal complexes. Russ Chem Bull 49, 375–377 (2000). https://doi.org/10.1007/BF02494692

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  • DOI: https://doi.org/10.1007/BF02494692

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