Abstract
The molecular complex C60·2[(Ph3P)AuCl] (1) was synthesized. The crystal and molecular structure of1 was established by X-ray diffraction analysis. At room temperature, the [60]fullerene molecules in complex1 are ordered due to π—π interactions between C60 and the phenyl rings of the chloro(triphenylphosphine)gold(1) molecules. The satellite structure, which accompanies the Cls photoelectron peak of complex1, is indicative of a partial suppression of a channel of losses due to π→π transition in the phenyl ring. The 1R spectral data indicate that either a charge is absent or the charge transfer to the fullerene molecule is negligible.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 365–369, February, 2000.
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Spitsina, N.G., Gritsenko, V.V., D'yachenko, O.A. et al. Synthesis, crystal structure, and spectral studies of the molecular complex of [60]fullerene with chloro(triphenylphosphine)gold(I), C60·2[(Ph3P)AuCl]. Russ Chem Bull 49, 367–371 (2000). https://doi.org/10.1007/BF02494690
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DOI: https://doi.org/10.1007/BF02494690