Abstract
Experimental gas-chromatographic data for 55 aromatic and aliphatic N-containing heterocyclic compounds and C5–C13 n-alkanes are analyzed. The polar constitutents of the boiling points (T pol) were calculated as the difference between the boiling points measured directly and the boiling points calculated from GC data obtained on a nonpolar column. Depending on the number, nature, and position of heteroatoms and alkyl groups in the rings and the structures of the molecules, theT pol values vary from −11° to +82°. The possibility of usingT pol values to estimate the physicochemical properties of compounds is discussed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp., 323–326, February, 2000.
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Zhuravleva, I.L. Evaluation of the polarity and boiling points of nitrogen-containing heterocyclic compounds by gas chromatography. Russ Chem Bull 49, 325–328 (2000). https://doi.org/10.1007/BF02494682
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DOI: https://doi.org/10.1007/BF02494682