Abstract
The kinetics of alkaline hydrolysis of ethylp-nitrophenyl ethylphosphonate in the reverse micellar system sodium dodecyl sulfate—hexanol—water was studied. At high pH and low water content, the process occurs at the surface layer and can satisfactorily be described by the pseudo-phase model equation.
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References
J. H. Fendler,Chem. Rev., 1987,87, 877.
L. Garsia-Rio, J. R. Leis, M. E. Pena, and E. Iglesias,J. Phys. Chem., 1993,97, 3437.
L. Ya. Zakharova, F. G. Valeeva, L. A. Kudryavtseva, N. L. Zakharchenko, and Yu. F. Zuev,Mendeleev Commun., 1998,8, 224.
H.-C. Hung, T.-M. Huang, and G.-G. Chang,J. Chem. Soc., Perkin Trans., 2, 1997, 2757.
E. Rodenas and E. Perez-Benito,J. Phys. Chem., 1991,95, 4552.
D. J. Jobe, H. B. Dunford, M. Pickard, and J. F. HolzWarth, inReactions in Compartmentalized Liquids, Ed. W. Knoche, Springer-Verlag, Heildelberg (Germany), 1989.
Microemulsions: Structure and Dynamics, Eds. S. E. Friberg and P. Bothorel CRC Press, Inc., Boca Raton, Florida, 1987, 320 p.
P. Stilbs,J. Colloid Interface Sci., 1982,87, 385.
C. A. Bunton and G. Savelli,Adv. Phys. Chem., 1986,22, 213.
A. Jada, J. Lang, and R. Zana,J. Phys. Chem., 1989,93, 10.
Y. Feldman, N. Kozlovich, I. Nir, N. Garti, V. Archipov, Z. Idiyatullin, Y. Zuev, and V. Fedorov,J. Phys. Chem., 1996,100, 3745.
F. G. Valeeva, V. E. Bel'skii, S. B. Fedorov, L. A. Kudryavtseva, G. S. Sakulin, and B. E. Ivanov,Izv. Akad. Nauk SSSR, Ser. Khim., 1988, 2752 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1988,37, 2478 (Engl. Transl.)].
K. Martinek, A. K. Yatsimirsky, A. V. Levashov, and I. V. Beresin,Micellization Solubilization, and Microemulsions, Ed. K. L. MIttal, Plenum Press, New York-London, 1977, 489.
C. Reichardt,Solvent Effects in Organic Chemistry, VCH, Weinheim, 1988.
C. K. Ingold,Structure and Mechanism in Organic Chemistry, Cornell University Press, Ithaca and London, 1969.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp 262–266, February, 2000.
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Zakharova, L.Y., Valeeva, F.G., Kudryavtseva, L.A. et al. Kinetics of alkaline hydrolysis of ethylp-nitrophenyl ethylphosphonate in the reverse micellar system: sodium dodecyl sulfate-hexanol-water. Russ Chem Bull 49, 265–269 (2000). https://doi.org/10.1007/BF02494669
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DOI: https://doi.org/10.1007/BF02494669