Abstract
Reactions of calix[4]resorcinolarene anions withpara-nitrophenyl carboxylates in the H2O−DMF medium were studied. The kinetics of this process was measured by optical spectroscopy and potentiometric titration; the step of formation of acylated calixarene and the subsequent step of its hydrolysis were detected. Self-association of long-chain calixarenes into micelles decreases their reactivity with respect to that of the monomers.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya No. 2, pp. 258–261, February, 2000.
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Mirgorodskaya, A.B., Kudryavtseva, L.A., Kazakova, E.K. et al. Reactions of calix[4]resorcinolarene anions with esters of carboxylic acids in H2O−DMF solvent. Russ Chem Bull 49, 261–264 (2000). https://doi.org/10.1007/BF02494668
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DOI: https://doi.org/10.1007/BF02494668