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CIDNP study of the Ni(acac)2-catalyzed reaction of triethylaluminum with chloroform

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Abstract

CIDNP effects were found in the Ni(acac)2-catalyzed reaction of Et3Al with CHCl3. The effects appear in the products of transformation of the diffusion radical pair of the ethyl and dichloromethyl radicals. The radical route is a side process in this reaction, and the main products, Et2AlCl, ethane, and ethylene, are formed by a nonradical route. A general mechanism of the reactions of Et3Al with CHCl3 and CCl4 including radical and ioncoordination processes was suggested.

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References

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. A. Sadykov & U. M. Dzhemilev

  2. Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. A. Sadykov & U. M. Dzhemilev

Authors
  1. R. A. Sadykov
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  2. U. M. Dzhemilev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1003–1006, May, 1999.

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Sadykov, R.A., Dzhemilev, U.M. CIDNP study of the Ni(acac)2-catalyzed reaction of triethylaluminum with chloroform. Russ Chem Bull 48, 995–997 (1999). https://doi.org/10.1007/BF02494653

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  • DOI: https://doi.org/10.1007/BF02494653

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