Abstract
The free radical formation in reactions of low-temperature (77–150 K) chlorination of monomers and phenols was studied by ESR and calorimetry. The schemes were suggested for multicentered synchronous reactions of radical formation in polymolecular complexes, whose initial composition was directly determined for the first time from the structure of the radicals formed and thermodynamic parameters of the total exothermic effect.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
S. V. Demidov, S. I. Kuzina, L. A. Serous, Yu. A. Filonenko, I. P. Kim, and A. I. Mikhailov,Khim. Prirod. Soedin., 1990,5, 671 [Chem. Nat. Compd., 1990,5 (Engl. Transl.)].
S. I. Kuzina, A. I. Mikhailov, and V. I. Gol'danskii,Dokl. Akad. Nauk SSSR, 1991,321, 1022 [Dokl. Chem., 1991 (Engl. Transl.)].
S. I. Kuzina, A. I. Mikhailov, and V. I. Gol'danskii,Eur. Polym. J., 1995,31, No. 6, 513.
S. I. Kuzina, A. P. Kharitonov, Yu. L. Moskvin, and A. I. Mikhailov,Izv. Akad. Nauk, Ser. Khim., 1996, 1714 [Russ. Chem. Bull., 1996,45, 1623 (Engl. Transl.)].
G. B. Sergeev and V. V. Smirnov,Molekulyarnoe galogenirovanie olefinov [Molecular Halogenation of Olefins], Izd-vo MGU, Moscow, 1985, 240 (in Russian).
R. B. Woodward and Hoffman,The Conservation of Orbital Symmetry, Weinheim, 1970.
V. D. Pokhodenko,Denoksil'nye radikaly [Phenoxyl Radicals], Naukova Dumka, Kiev, 1969, 192 (in Russian).
I. Suzuki, J. Ono, and T. Keii,J. Phys. Chem., 1970,74, No. 15, 2923.
J. Pilar, J. Rotschova, and J. Pospisil,34th IUPAC Int. Symp. Macromol. Prague, 13–18 July, 1992, Book Abstr. S. I., 1992, 773.
S. Ya. Pshezhetskii, A. G. Kotov, V. K. Milinchuk, V. A. Roginskii, and V. I. Tupikov,EPR svobodnykh radikalov v radiatsionnoi khimii [ESR of Free Radicals in Radiation Chemistry], Khimiya, Moscow, 1972, 480 (in Russian).
C. Bressler, W. G. Lawrence, and N. Schwentner,Sovremennye problemy i perspektivy khimii nizkikh temperatur, Sb. nauchn. trudov [Modern Problems and Challenges of Low-Temperature Chemistry, Collection of Scientific Works], Izd-vo MGU, Moscow, 1994, 97.
Author information
Authors and Affiliations
Additional information
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 335–339, February, 1999.
Rights and permissions
About this article
Cite this article
Kuzina, S.I., Demidov, S.V., Denisov, N.N. et al. Synchronous reactions of free radical formation upon low-temperature chlorination of aromatic and olefinic hydrocarbons. Russ Chem Bull 48, 334–338 (1999). https://doi.org/10.1007/BF02494559
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02494559