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Mechanism of formation ofo-semiquinone metal complexes under mechanical pulse action on metal oxide-quinone-pyrocatechol systems

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The possibility of the mechanochemical synthesis of metal-containing mono-, bi-, and triradicals under mechanical pulse action on mixtures of metal oxides (CuO, ZnO, CdO, PbO, Al2O3, Ga2O3, Sb2O3, Bi2O3, Cr2O3, TiO2, GeO2, ZrO2, or SnO2) with quinone and pyrocatechol was examined. The reaction products are formed both on the surface of metal oxides and as individual solid phases. The mechanism of chemical processes that occur under the action of a single elastic wave pulse is proposed.

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Authors and Affiliations

  1. Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 70 ul. Profsoyznaya, 117393, Moscow, Russian Federation

    A. I. Aleksandrov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. I. Prokof'ev & N. N. Bubnov

  3. Center for Materials Research, Norfolk State University, 23504, Norfolk, Virginia, USA

    R. R. Rakhimov

  4. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    I. A. Aleksandrov, A. A. Dubinskii & Ya. S. Lebedev

Authors
  1. A. I. Aleksandrov
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  2. A. I. Prokof'ev
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  3. N. N. Bubnov
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  4. R. R. Rakhimov
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  5. I. A. Aleksandrov
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  6. A. A. Dubinskii
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  7. Ya. S. Lebedev
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Additional information

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 324–330, February, 1999.

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Aleksandrov, A.I., Prokof'ev, A.I., Bubnov, N.N. et al. Mechanism of formation ofo-semiquinone metal complexes under mechanical pulse action on metal oxide-quinone-pyrocatechol systems. Russ Chem Bull 48, 323–329 (1999). https://doi.org/10.1007/BF02494557

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  • DOI: https://doi.org/10.1007/BF02494557

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