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Acid-base interactions in the methanesulfonic acid-propylene carbonate system

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The methanesulfonic acid (MSA)—propylene carbonate (PC) system with component concentrations of 0–100% was studied at 30°C using the Multiple Attenuated Total Reflection (MATR) IR spectroscopy. The formation of a strong 1∶1 molecular complex of MSA with PC was established. In the presence of an excess of the acid, a second MSA molecule adds to this complex to give the molecular complex (2MSA)·PC. When excess propylene carbonate is used, the MSA·PC complex is solvated by a propylene carbonate molecule. No protonation of the base or formation of complexes with a strong symmetrical H bond was observed. Continuous absorption was not detected in IR spectra of the solutions.

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References

  1. G. V. Yukhnevich, E. G. Tarakanova, V. D. Maiorov, and N. B. Librovich,J. Mol. Struct., 1992,265, 237.

    Article  CAS  Google Scholar 

  2. G. V. Yukhnevich, E. G. Tarakanova, V. D. Maiorov, and N. B. Librovich,Usp. Khim., 1995,64, 963, [Russ. Chem. Rev., 1995,65 (Engl. Transl.)].

    CAS  Google Scholar 

  3. A. P. Kirilova, V. D. Maiorov, A. I. Serebryanskaya, N. B. Librovich, and E. N. Gur'yanova,Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 1493 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985,34, 1366 (Engl. Transl.)].

  4. A. P. Kirilova, V. D. Maiorov, A. I. Serebryanskaya, N. B. Librovich, and E. N. Gur'yanova,Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 2724 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987,36, 2525 (Engl. Transl.)].

  5. A. P. Kirilova, V. D. Maiorov, A. I. Serebryanskaya, N. B. Librovich, and E. N. Gur'yanova,Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 2435 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986,35, 2226 (Engl. Transl.)].

  6. V. D. Maiorov and I. S. Kislina,Khim. Fizika, 1993,11, 660 [Sov. J. Chem. Phys., 1993,11, 956 (Engl. Transl.)].

    Google Scholar 

  7. V. D. Maiorov, S. G. Sysoeva, O. N. Temkin, and I. S. Kislina,Izv. Akad. Nauk, Ser. Khim., 1993, 1577 [Russ. Chem. Bull., 1993,42, 1511 (Engl. Transl.)].

    Google Scholar 

  8. V. D. Maiorov, I. S. Kislina, S. G. Sysoeva, and O. N. Temkin,Izv. Akad. Nauk, Ser. Khim., 1995, 1757 [Russ. Chem. Bull., 1995,44, 1688 (Engl. Transl.)].

    Google Scholar 

  9. V. V. Burdin, I. S. Kislina, V. D. Maiorov, S. G. Sysoeva, and N. B. Librovich,Izv. Akad. Nauk, Ser. Khim., 1998, 2484 [Russ. Chem. Bull., 1998,47, 2404 (Engl. Transl.)].

    Google Scholar 

  10. Coordination Chemistry in Nonaqueous Solutions, Ed. V. Gutmann, Springer-Verlag, Wien-New York, 1968.

    Google Scholar 

  11. N. J. Harrick,Internal Reflection Spectroscopy, Wiley Interscience, New York-London-Sydney, 1967.

    Google Scholar 

  12. A. Simon and H. Kriegsmann,Chem. Ber., 1956,B. 89, 2384.

    CAS  Google Scholar 

  13. R. A. Pethrick and A. D. Wilson,Spectrochim. Acta, 1974,30A, 1073.

    CAS  Google Scholar 

  14. D. M. Minkin, inAlkilenkarbonaty [Alkylene Carbonates], Nauka, Leningrad, 1975, 164 (in Russian).

    Google Scholar 

  15. W. A. Proele, C. F. Adams, and B. H. Shoemaker,Industrial and Engineering Chem., 1948,40, 1129.

    Article  Google Scholar 

  16. M. I. Vinnik,Usp. Khim., 1966,35, 1922 [Russ. Chem. Rev., 1966,35 (Engl. Transl.)].

    CAS  Google Scholar 

  17. S. Nafarajan and A. W. Iache,The Chemistry of Nonaqueous Solvents, Ed. J. J. Lagowski, Acad. Press., 1978, p. 54.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    V. D. Maiorov, G. I. Voloshenko, A. P. Kirilova & N. B. Librovich

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  1. V. D. Maiorov
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  2. G. I. Voloshenko
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  3. A. P. Kirilova
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  4. N. B. Librovich
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 313–318 February, 1999.

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Maiorov, V.D., Voloshenko, G.I., Kirilova, A.P. et al. Acid-base interactions in the methanesulfonic acid-propylene carbonate system. Russ Chem Bull 48, 312–317 (1999). https://doi.org/10.1007/BF02494555

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  • DOI: https://doi.org/10.1007/BF02494555

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