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Self-propagating high-temperature synthesis in the solid-phase triphenylphosphine-chloramine system

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The macrokinetics and products of self-propagating high-temperture synthesis (SHS) in the solid-phase triphenylphosphine—chloramine system were studied by TGA-DTA, XRD, and31P NMR techniques. The temperature of SHS ignition (59°C), the velocity of reaction waves (1.6–5.0 mm s−1), and the maximum temperature (155–239°C) in the SHS wave were measured. The chemical composition of the product obtained was established: phosphine oxide, triphenyl-N-(phenylsulfoyl)-phosphinimine, benzenesulfonamide, NaCl, and water. The scheme of chemical reactions occurring during SHS was proposed.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    E. G. Klimchuk & A. G. Merzhanov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. A. Khodak

Authors
  1. E. G. Klimchuk
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  2. A. A. Khodak
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  3. A. G. Merzhanov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 301–305, February, 1999.

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Klimchuk, E.G., Khodak, A.A. & Merzhanov, A.G. Self-propagating high-temperature synthesis in the solid-phase triphenylphosphine-chloramine system. Russ Chem Bull 48, 300–304 (1999). https://doi.org/10.1007/BF02494553

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  • DOI: https://doi.org/10.1007/BF02494553

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