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Electrochemical reduction of CO2 in the presence of 1,3-butadiene using a hydrogen anode in a nonaqueous medium

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The possibility of anodic generation of a solvated proton on a gas-diffusion electrode in an aprotic medium in the presence of carbon dioxide and 1,3-butadiene has been demonstrated. Formic acid was shown to be the only product of the reaction in the initially aprotic medium with the use of a hydrogen gas-diffusion anode. The influence of the counterion on the reactivity of the CO2 .− radical anion in electrocarboxylation was shown experimentally.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071, Moscow, Russian Federation

    V. A. Grinberg, V. M. Mazin, E. I. Mysov & S. R. Sterlin

  2. DuPont Research Center, 9880-0262, Wilmington, DE, USA

    T. A. Koch

Authors
  1. V. A. Grinberg
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  2. T. A. Koch
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  3. V. M. Mazin
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  4. E. I. Mysov
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  5. S. R. Sterlin
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 295–300, February, 1999.

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Grinberg, V.A., Koch, T.A., Mazin, V.M. et al. Electrochemical reduction of CO2 in the presence of 1,3-butadiene using a hydrogen anode in a nonaqueous medium. Russ Chem Bull 48, 294–299 (1999). https://doi.org/10.1007/BF02494552

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  • DOI: https://doi.org/10.1007/BF02494552

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