Abstract
The parameters of the reaction ofpara-substituted 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate in toluene catalyzed by reversed micelles of polyethylene glycol-600 monolaurate depend on the nucleophile structure. The efficiency of the catalytic action increases in the series of substitutes C9H19 i<H<Cl. An increase in the catalytic activity of micelles in the region of structural rearrangement of micelle aggregates was observed.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 275–278, February, 1999.
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Zhil'tsova, E.P., Kudryavtseva, L.A. & Shagidullina, R.A. The inverted micellar catalysis of the reaction of 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate. Russ Chem Bull 48, 274–277 (1999). https://doi.org/10.1007/BF02494546
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DOI: https://doi.org/10.1007/BF02494546