Russian Chemical Bulletin

, Volume 47, Issue 10, pp 2015–2016 | Cite as

Catalytic activity of various Lewis acids in the phosphorylation of primary polyfluoroalkanols with phosphoryl chloride

  • I. Yu. Kudryavtsev
  • L. S. Zakharov
  • M. I. Kabachnik
Brief Communications

Abstract

The catalytic activity of SnCl2, SnCl4, SbCl3, SbCl5, and BiCl3 in the reaction of 2,2,3,3,4,4,4-heptafluoroubutanol with POCl3 was studied. The mechanism of this reaction is discussed. Strong Lewis acids were found to be less active catalysts.

Key words

catalytic phosphorylation electrophilic catalysis Lewis acids polyfluoroalkanols 

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • I. Yu. Kudryavtsev
    • 1
  • L. S. Zakharov
    • 1
  • M. I. Kabachnik
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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