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Catalytic activity of various Lewis acids in the phosphorylation of primary polyfluoroalkanols with phosphoryl chloride

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Abstract

The catalytic activity of SnCl2, SnCl4, SbCl3, SbCl5, and BiCl3 in the reaction of 2,2,3,3,4,4,4-heptafluoroubutanol with POCl3 was studied. The mechanism of this reaction is discussed. Strong Lewis acids were found to be less active catalysts.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    I. Yu. Kudryavtsev, L. S. Zakharov & M. I. Kabachnik

Authors
  1. I. Yu. Kudryavtsev
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  2. L. S. Zakharov
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  3. M. I. Kabachnik
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Additional information

On 90th birthday of Academician M. I. Kabachnik.

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2070–2071, October, 1998.

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Kudryavtsev, I.Y., Zakharov, L.S. & Kabachnik, M.I. Catalytic activity of various Lewis acids in the phosphorylation of primary polyfluoroalkanols with phosphoryl chloride. Russ Chem Bull 47, 2015–2016 (1998). https://doi.org/10.1007/BF02494520

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  • DOI: https://doi.org/10.1007/BF02494520

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