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Russian Chemical Bulletin

, Volume 47, Issue 10, pp 2000–2006 | Cite as

Synthesis, spectral characteristics, and crystal structure of the hexanuclear complex MeSi[η15-C5H4(CO)2Fe(η15-C5H5)Mn(CO)3]3

  • T. Yu. Orlova
  • Yu. S. Nekrasov
  • P. V. Petrovskii
  • M. G. Ezernitskaya
  • Z. A. Starikova
  • A. I. Yanovsky
Organometallic Chemistry

Abstract

The reaction of MeSiCl3 with 3 equivalents of LiC5H4(CO)2Fe(η15-C5H4)Mn(CO)3 afforded the hexanuclear complex MeSi[η15-C5H4(CO)2Fe(η15-C5H5)Mn(CO)3]3. The structure of the resulting complex was established by1H and13C NMR and IR spectroscopy and by X-ray diffraction analysis.

Key words

“ladder” complex crystal structure 

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Copyright information

© Plenum Publishing Corporation 1998

Authors and Affiliations

  • T. Yu. Orlova
    • 1
  • Yu. S. Nekrasov
    • 1
  • P. V. Petrovskii
    • 1
  • M. G. Ezernitskaya
    • 1
  • Z. A. Starikova
    • 1
  • A. I. Yanovsky
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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