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Synthesis and transformations of acyloxy(chloromethyl)phosphonates and acyloxy(chloromethyl)phosphinates

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Abstract

The reactions ofO-phenyl chloromethylphosphonochloridate and bis(chloromethyl)phosphinous chloride with sodium acetate afford the corresponding acyloxyphosphonates and acyloxyphosphinates, which are readily transformed due to disproportionation into pyrophosphonates and pyrophosphinates.

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References

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Research Center of the Russian Academy of Sciences, 8 ul. Acad. Arbuzova, 420088, Kazan, Russian Federation

    N. A. Khailova, A. A. Shaimardanova & M. A. Pudovik

Authors
  1. N. A. Khailova
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  2. A. A. Shaimardanova
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  3. M. A. Pudovik
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp 2383–2385, November, 1998.

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Khailova, N.A., Shaimardanova, A.A. & Pudovik, M.A. Synthesis and transformations of acyloxy(chloromethyl)phosphonates and acyloxy(chloromethyl)phosphinates. Russ Chem Bull 47, 2311–2312 (1998). https://doi.org/10.1007/BF02494306

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  • DOI: https://doi.org/10.1007/BF02494306

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