Russian Chemical Bulletin

, Volume 47, Issue 11, pp 2311–2312 | Cite as

Synthesis and transformations of acyloxy(chloromethyl)phosphonates and acyloxy(chloromethyl)phosphinates

  • N. A. Khailova
  • A. A. Shaimardanova
  • M. A. Pudovik
Brief Communications


The reactions ofO-phenyl chloromethylphosphonochloridate and bis(chloromethyl)phosphinous chloride with sodium acetate afford the corresponding acyloxyphosphonates and acyloxyphosphinates, which are readily transformed due to disproportionation into pyrophosphonates and pyrophosphinates.

Key words

chloromethylphosphonates bis(chloromethyl)phosphinates reaction disproportionation pyrophosphonates pyrophosphinates 


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Copyright information

© Kluwer Academic/Plenum Publishers 1999

Authors and Affiliations

  • N. A. Khailova
    • 1
  • A. A. Shaimardanova
    • 1
  • M. A. Pudovik
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryKazan' Research Center of the Russian Academy of SciencesKazanRussian Federation

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