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Synthesis and molecular structure of the complex YbI(bipy)(DME)2

  • Organometallic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The reaction of the naphthalene complex of ytterbium, [Yb(DME)2]2(μ-C10H8), with 2,2′-bipyridine in 1,2-dimethoxyethane afforded the YbII complex containing the 2,2′-bipyridine radical anion. The resulting complex YbI(bipy)(DME)2 was characterized by IR and ESR spectroscopy, X-ray diffraction analysis, and magnetochemistry.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhny Novgorod, Russian Federation

    T. V. Petrovskaya, I. L. Fedyushkin, V. I. Nevodchikov, M. N. Bochkarev & N. V. Borodina

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907, Moscow, Russian Federation

    I. L. Eremenko & S. E. Nefedov

Authors
  1. T. V. Petrovskaya
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  2. I. L. Fedyushkin
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  3. V. I. Nevodchikov
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  4. M. N. Bochkarev
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  5. N. V. Borodina
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  6. I. L. Eremenko
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  7. S. E. Nefedov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2341–2344, November, 1998.

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Petrovskaya, T.V., Fedyushkin, I.L., Nevodchikov, V.I. et al. Synthesis and molecular structure of the complex YbI(bipy)(DME)2 . Russ Chem Bull 47, 2271–2273 (1998). https://doi.org/10.1007/BF02494294

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  • DOI: https://doi.org/10.1007/BF02494294

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