Skip to main content
SpringerLink
Log in

Influence of a water vapor admixture in the carrier gas on capacity coefficients of polar organic compounds

  • Physical Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The influence of a water vapor admixture in helium, nitrogen, and carbon dioxide on capacity coefficients of C3−C5 alcohols and pyridine during chromatography process in capillary columns with polar (PEG-20M) and nonpolar (SE-30) stationary phases was studied. The introduction of a water admixture into the carrier gas, increases the capacity coefficient of polar organic compounds on the capillary column with PEG-20M and has almost no effect on this value in the case of SE-30. The change in retention of polar organic compounds on the capillary column with the PEG-20M polar phase occurs due to a change in the properties of the stationary phase when it adsorbs water from the mobile phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. G. Berezkin, A. A. Korolev, and I. V. Malyukova,J. Microcolumn. Sep., 1996,8, 389.

    Article  CAS  Google Scholar 

  2. V. G. Berezkin, A. A. Korolev, and I. V. Malyukova,J. High Resol. Chromatogr., 1997,20, 333.

    Article  CAS  Google Scholar 

  3. V. G. Berezkin, A. A. Korolev, and I. V. Malyukova,Neftekhimiya, 1995,35, 463 [Petrochemistry, 1995,35 (Engl. Transl.)].

    CAS  Google Scholar 

  4. V. G. Berezkin and A. A. Korolev,Zh. Anal. Khim., 1995,50, 1057 [Russ. J. Anal. Chem., 1995,50 (Engl. Transl.)].

    Google Scholar 

  5. V. G. Berezkin,Gas-Liquid-Solid Chromatography, M. Dekker, New York, 1991.

    Google Scholar 

  6. D. H. Everett, B. W. Gainey, and C. L. Young,Trans. Faraday Soc., 1968,64, 2667.

    Article  CAS  Google Scholar 

  7. A. J. B. Cruikshank, B. W. Gainey, C. P. Hicks, T. M. Letcher, R. W. Moody, and C. L. Young,Trans. Faraday Soc., 1969,65, 1014.

    Article  Google Scholar 

  8. J. H. Dymond and E. B. Smith,The Virial Coefficients of Pure Gasses and Mixtures, Clarendon Press, Oxford, 1980.

    Google Scholar 

  9. J. R. Conder and C. L. Young,Physicochemical Measurement by Gas Chromatography, J. Wiley, Chichester, 1978.

    Google Scholar 

  10. M. S. Vigdergauz, A. V. Garusov, V. A. Ezrets, and V. I. Semkin,Gazovaya khromatografiya s neideal'nymi elyuentami [Gas Chromatography with Nonideal Eluents], Nauka, Moscow, 1980 (in Russian).

    Google Scholar 

  11. Modern Practice of Gas Chromatography, Ed. R. L. Grob, J. Wiley, New York, 1995.

    Google Scholar 

  12. V. G. Berezkin and A. A. Korolev,Zh. Fiz. Khim., 1995,69, 2052 [Russ. J. Phys. Chem., 1995,69 (Engl. Transl.)].

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912, Moscow, Russian Federation

    V. G. Berezkin & A. A. Korolev

Authors
  1. V. G. Berezkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Korolev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2258–2261, November, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Berezkin, V.G., Korolev, A.A. Influence of a water vapor admixture in the carrier gas on capacity coefficients of polar organic compounds. Russ Chem Bull 47, 2189–2192 (1998). https://doi.org/10.1007/BF02494278

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02494278

Key words

Search

Navigation