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Preparation and chromatographic characteristics of calix[4]arene polysiloxane as stationary phases for capillary gas chromatography

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Summary

Two new kinds of calix[4]arene derivatives, 5, 11, 17, 23-tetra-tert-butyl-25,27-bis(isopropylcarbamoyl-methoxy)-26,28-diundecenyloxy calix[4]arene (C[4]A) and 25,27-dibutoxy-5, 11, 17, 23-tetra-tert-butyl-26,28-diundecenyloxy calix[4]arene (C[4]B0, are prepared and then are polymized by two different processes. Three calix[4]arene polysiloxane stationary phases for capillary gas chromatography are obtained. Their chromatographic characteristics, including column efficiency, polarity, selectivity, glass-transition temperature and thermal stability are studied. Retention mechanisms are also discussed.

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, P.R. China

    X. H. Lai, L. Lin & C. Y. Wu

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  1. X. H. Lai
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  2. L. Lin
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  3. C. Y. Wu
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Lai, X.H., Lin, L. & Wu, C.Y. Preparation and chromatographic characteristics of calix[4]arene polysiloxane as stationary phases for capillary gas chromatography. Chromatographia 50, 82–88 (1999). https://doi.org/10.1007/BF02493622

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  • DOI: https://doi.org/10.1007/BF02493622

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