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Determination of organochlorine pesticides by gas chromatography with solid-phase microextraction

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  • Gas Chromatography
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Summary

A study of different extraction techniques for the determination of a selected group of organochlorine compounds in surface waters is presented. Comparison of liquid-liquid extraction (LLE) with solid-phase extraction (SPE) and solid-phase microextraction (SPME) with fibers of different polarity shows that SPME with a recently commercialised fiber of polydimethylsiloxane divinylbenzene allows these compounds to be determined in surface waters with good extraction efficiencies. Extraction time, effect of temperature, ionic strength and pH were optimised, allowing quantification in agricultural effluents in the range 1.0–60 ng·L−1.

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References

  1. Barceló, D.J. Chromatogr. 1993,643, 117–143.

    Article  Google Scholar 

  2. Beltrán, J.; López, F. J.; Hernández, F.J. Chromatogr. A 2000,885, 389–404.

    Article  Google Scholar 

  3. Fielding, M.; Barceló, D.; Helweg, A.; Galassi, S.; Torstensson, L.; van Zoonen, P.; Wolter, R.; Angeletti, G.Pesticides in Ground and Drinking Water (Water Pollution Research Report, 27),Commission of the European Communities, Brussels,1992, 1-136.

    Google Scholar 

  4. Gray, N.F.Drinking Water Quality Problems and Solutions, John Wiley and Sons, London,1994, 313.

    Google Scholar 

  5. Magdic, S.; Pawliszan, J.B.J. Chromatogr. A 1996,723, 111–122.

    Article  CAS  Google Scholar 

  6. Boyd-Boland, A.A.; Magdic, S.; Pawliszyn, J.,Analyts 1996,121, 929–938.

    CAS  Google Scholar 

  7. Boyd-Boland, A.A.; Pawliszyn, J.J. Chromatogr. A 1995,704, 163–172.

    Article  CAS  Google Scholar 

  8. Page, B.D.; Lacroix, G.J. Chromatogr. A 1997,757, 173–182.

    Article  Google Scholar 

  9. Popp, P.; Kalbitz, K.; Oppermann, G.J. Chromatogr. A 1994,687, 133–140.

    Article  CAS  Google Scholar 

  10. Aguilar, C.; Peñalver, S.; Pocurull, E.; Borrul, F.; Marce, R.M.J. Chromatogr. A 1998,795, 105–115.

    Article  CAS  Google Scholar 

  11. Jackson, G.P.; Andrews, A.R.J.Analyst 1998,123, 1085–1090.

    Article  CAS  Google Scholar 

  12. Shirey, R.E.J. High Resolut. Chromatogr. 1995,18, 495–501.

    Article  CAS  Google Scholar 

  13. Almeida, M.T.; Conceicao, P.M.; Alpendurada, M.F.Analusis 1997,25, 51–62.

    CAS  Google Scholar 

  14. Young, R.; Lopez Avila, V.; Beckert, W.F.J. High Resolut. Chromatogr. 1996,19, 247–253.

    Article  CAS  Google Scholar 

  15. Dugay, J.; Miege, C.; Hennion, M.C.J. Chromatogr. A 1998,795, 27–42.

    Article  CAS  Google Scholar 

  16. Federal Register, Rules and Regulations, Method 608, Organochlorine Pesticides and PCBs1984,Vol. 29, No 209, 43321.

  17. Federal Register, Rules and Regulations, Method 625, Base/Neutrals and Acids1984,Vol. 49, No 209, 43385.

  18. Liska, L.; Krupcik, J; Laclercq, P.A.J. High Resolut. Chromatogr. 1989,12, 577–583.

    Article  CAS  Google Scholar 

  19. Mañes, J.; Yolanda, P.; Mottó, J.C.; Font, G.J. High Resolut. Chromatogr. 1990,13, 843–849.

    Article  Google Scholar 

  20. Jurtoft, R.E.; Gouw, T.W.Anal. Chem. 1976,48, 2195–2200.

    Article  Google Scholar 

  21. Onuska, F.I.J. High. Resolut. Chromatogr. 1984,7, 660–667.

    Article  CAS  Google Scholar 

  22. Commission on Microchemical Techniques in Trace Analysis,Pure Appl. Chem. 1988,60, 1438–1446.

    Google Scholar 

  23. Font, G.; Mañes, J.; Moltó, J.C.; Picó, Y.J. Chromatogr. 1993,642, 135–161.

    Article  CAS  Google Scholar 

  24. Arthur, C.L.; Pawliszyn, J.Anal. Chem. 1990,62, 2145–2148.

    Article  CAS  Google Scholar 

  25. Zhang, Z.; Pawliszyn, J.Anal. Chem. 1993,65, 1843–1852.

    Article  CAS  Google Scholar 

  26. Pawliszyn, J.Trends Anal. Chem. 1995,14, 113–122.

    CAS  Google Scholar 

  27. Beltrán, J.; López, F.J.; Hernández, F.J. Chromatogr. A 2000,885, 389–404.

    Article  Google Scholar 

  28. de Fátima Alpendurada, M.J. Chromatogr. A 2000,889, 3–14.

    Article  Google Scholar 

  29. LaGrega, M.D.; Buckingham, P.L.; Evans, J.C.Hozardous Waste Managent, McGraw-Hill, New York 1994.

    Google Scholar 

  30. Barnabas, I.J.; Dean, J.R.; Fowlis, I.A.; Owen, S.P.J. Chromatogr. A 1995,705, 305–312.

    Article  CAS  Google Scholar 

  31. Magdic, S.; Boyd-Boland, A.; Jinno, K.; Pawliszyn, J.B.J. Chromatogr. A 1996,736, 219–228.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Nutrition and Food Science, University of La Laguna, 38071, Tenerife, Spain

    J. P. Pérez-Trujillo, S. Frías, M. J. Sáchez, J. E. Conde & M. A. Rodríguez-Delgado

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  1. J. P. Pérez-Trujillo
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  2. S. Frías
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  3. M. J. Sáchez
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  4. J. E. Conde
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  5. M. A. Rodríguez-Delgado
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Pérez-Trujillo, J.P., Frías, S., Sáchez, M.J. et al. Determination of organochlorine pesticides by gas chromatography with solid-phase microextraction. Chromatographia 56, 191–197 (2002). https://doi.org/10.1007/BF02493211

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  • DOI: https://doi.org/10.1007/BF02493211

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