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Other chiral selectors

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References

  1. Gassman, E.; Kuo, J.E.; Zare, R.N. Electrokinetic Separation of Chiral Compounds,Science 1985,230, 813–814.

    Google Scholar 

  2. Gozel, P.; Gassman, E.; Michelsen, H.; Zare, R.N. Electrokinetic Resolution of Amino Acid Enantiomers with Copper (II)-Aspartame Support Electrolyte,Anal. Chem. 1987,59, 44–49.

    Article  CAS  Google Scholar 

  3. Schmid, M.G.; Gübitz, G. Direct Enantiomer Separation of Underivatized Amino Acids by Capillary Zone Electrophoresis Based on Ligand Exchange,Enantiomer 1996,1, 23–27.

    CAS  Google Scholar 

  4. Végvári, A.; Schmid, M.G.; Kilár, F.; Gübitz, G. Chiral separation of α-amino acids by ligand-exchange capillary electrophoresis usingN-(2-hydroxy-octyl)-L-4-hydroxyproline as a selector,Electrophoresis 1998,19, 2109–2112.

    Article  Google Scholar 

  5. Chen, Z.; Lin, J. -M.; Uchiyama, K.; Hobo, T. Simultaneous Separation of Sixteen Positional and Optical Isomers of the Tryptophan Family by Ligand-Exchange Micellar Electrokinetic Chromatography,Chromatographia 1999,49, 436–443.

    Article  CAS  Google Scholar 

  6. Chen, Z.; Lin, J. -M.; Uchiyama, K.; Hobo, T. Separation Behaviour of Amino Acid Enantiomers in Ligand Exchange Micellar Electrokinetic Chromatography,J. Microcolumn Separations 1999,11, 534–540.

    Article  CAS  Google Scholar 

  7. Otsuka, K.; Terabe, S., Effects of methanol and urea on optical resolution of phenylthiohydantoin-DL-amino acids by micellar electrokinetic chromatography with sodiumN-dodecanoyl-L-valinate,Electrophoresis 1990,11, 982–984.

    Article  CAS  Google Scholar 

  8. Otsuka, K.; Kawahara, J.; Tatekawa, K.; Terabe, S. Chiral separations by micellar electrokinetic chromatography with sodium N-dodecanoyl-L-valinate,J. Chromatogr. 1991,559, 209–214.

    Article  CAS  Google Scholar 

  9. Mazzeo, J.R.; Grover, E.R.; Swartz, M.E.; Petersen, J.S., Novel chiral surfactant for the separation of enantiomers by micellar electrokinetic chromatography,J. Chromatogr. A 1994,680, 125–135.

    Article  CAS  Google Scholar 

  10. Wang, J.; Warner, I.M. Combined polymerized chiral micelle and γ-cyclodextrin for chiral separations in capillary electrophoresis,J. Chromatogr. A 1995,711, 297–304.

    Article  CAS  Google Scholar 

  11. Shamsi, S.A.; Warner, I.M. Monomeric and polymeric chiral surfactants as pseudo-stationary phases for chiral separations,Electrophoresis 1997,18, 853–872.

    Article  CAS  Google Scholar 

  12. Nishi, H.; Fukuyama, T.; Matsuo, M.; Terabe, S. Chiral Separation of Optical Isomeric Drugs Using Micellar Electrokinetic Chromatography and Bile Salts,J. Microcolumn Separations 1989,1, 234–241.

    Article  CAS  Google Scholar 

  13. Amini, A.; Beijersten, I.; Pettersson, C.; Westerlund, D. Enantiomeric separation of local anaesthetic drugs by micellar electrokinetic capillary chromatography with taurodeoxycholate as chiral selector,J. Chromatogr. A 1996,737, 301–313.

    Article  CAS  Google Scholar 

  14. Okafo, G.N.; Camilleri, P. Direct Chiral Resolution of Amino Acid Derivatives by Capillary Electrophoresis,J. Microcolumn Separations 1993,5, 149–153.

    Article  CAS  Google Scholar 

  15. Otsuka, K.; Terabe, S. Enantiomeric resolution by micellar electrokinetic chromatography with chiral surfactants,J. Chromatogr. 1990,515, 221–226.

    Article  CAS  Google Scholar 

  16. Mechref, Y.; Rassi, Z.E. Comparison of alkylglycoside surfactants in enantioseparation by capillary electrophoresis,Electrophoresis 1997,18, 912–918.

    Article  CAS  Google Scholar 

  17. Ingelse, B.A.; Flieger, M.; Claessen, H.A.; Everaerts, F.M. Ergot alkaloids as chiral selectors in capillary electrophoresis determination of separation mechanism,J. Chromatogr. A 1996,755, 251–259.

    Article  CAS  Google Scholar 

  18. Ingelse, B.A.; Reijenga, J.C.; Everaerts, F.M. Reversed determination of the formation constants of 1-allyterguride with mandelic acid optical isomers using capillary electrophoresis,J. Chromatogr. A 1997,772, 179–184.

    Article  CAS  Google Scholar 

  19. Nair, U.B.; Armstrong, D.W.; Hinze, W.L. Characterization and Evaluation ofd-(+)-Tubocurarine Chloride as a Chiral Selector for Capillary Electrophoretic Enantioseparations,Anal. Chem. 1998,70, 1059–1065.

    Article  CAS  Google Scholar 

  20. Kuhn, R.; Erni, F.; Bereuter, T.; Häusler, J. Chiral Recognition and Enantiomeric Resolution Based on Host-Guest Complexation with Crown Ethers in Capillary Zone Electrophoresis,Anal. Chem. 1992,64, 2815–2820.

    Article  CAS  Google Scholar 

  21. Kuhn, R.; Stoecklin, F.; Erni, F. Chiral Separations by Host-Guest Complexation with Cyclodextrin and Crown Ether in Capillary Zone Electrophoresis,Chromatographia 1992,33, 32–36.

    Article  CAS  Google Scholar 

  22. Verleysen, K.; Vandijck, J.; Schelfaut, M.; Sandra, P. Enantiomeric Separations in Capillary Electrophoresis Using 18-Crown-6-tetracarboxylic Acid (18C6H4) as Buffer Additive,J. High Resol. Chromatogr. 1998,21, 323–331.

    Article  CAS  Google Scholar 

  23. Verleysen, K.; Sandra, P. Enantiomeric Separation of Some Amino Acids and Derivatives by Capillary Electrophoresis with 18-Crown-6-Tetracarboxylic Acid as Chiral Selector,J. Microcolumn Separations 1999,11, 37–43.

    Article  CAS  Google Scholar 

  24. Barker, G.E.; Russo, P.; Hartwick, R.A. Chiral Separation of Leucovorin with Bovine Serum Albumin Using Affinity Capillary Electrophoresis,Anal. Chem. 1992,64, 3024–3028.

    Article  CAS  Google Scholar 

  25. Vespalec, R.; Sustacek, V.; Bocek, P. Prospects of dissolved albumin as a chiral selector in capillary zone electrophoresis,J. Chromatogr. 1993,638, 255–261.

    Article  CAS  Google Scholar 

  26. Valtcheva, L.; Mohammad, J.; Pettersson, G.; Hjertén, S. Chiral separation of β-blockers by high-performance capillary electrophoresis based on non-immobilized cellulase as enantioselective protein,J. Chromatogr. 1993,638, 263–267.

    Article  CAS  Google Scholar 

  27. Tanaka, Y.; Terabe, S.; Partial separation zone technique for the separation of enantiomers by affinity electrokinetic chromatography with proteins as chiral pseudo-stationary phases,J. Chromatogr. A 1995,694, 277–284.

    Article  CAS  Google Scholar 

  28. Amini, A.; Pettersson, C.; Westerlund, D. Enantioresolution of disopyramide by capillary affinity electrokinetic chromatography with human α1-acid glycoprotein (AGP) as chiral selector applying a partial filling technique,Electrophoresis 1997,18, 950–957.

    Article  CAS  Google Scholar 

  29. Haginaka, J.; Kanasugi, N. Separation of basic drug enantiomers by capillary zone electrophoresis using ovoglycoprotein as a chiral selector,J. Chromatogr. A 1997,782, 281–288.

    Article  CAS  Google Scholar 

  30. Tanaka, Y.; Terabe, S. Studies on Enantioselectivities of Avidin, Avidin-Biotin Complex and Streptavidin by Affinity Capillary Electrophoresis,Chromatographia 1999,49, 489–495.

    Article  CAS  Google Scholar 

  31. Tanaka, Y.; Matsubara, N.; Terabe, S. Separation of enantiomers by affinity electrokinetic chromatography using avidin,Electrophoresis 1994,15, 848–853.

    Article  CAS  Google Scholar 

  32. Armstrong, D.W.; Rundlett, K.L.; Chen, J. -R. Evaluation of the Macrocyclic Antibiotic Vancomycin as a Chiral Selector for Capillary Electrophoresis,Chirality 1994,6, 496–509.

    Article  CAS  Google Scholar 

  33. Armstrong, D.W.; Rundlett, K.; Reid III, G.L. Use of a Macrocyclic Antibiotic, Rifamycin B, Indirect Detection for the Resolution of Racemic Amino Alcohols by CE,Anal. Chem. 1994,66, 1690–1695.

    Article  CAS  Google Scholar 

  34. Armstrong, D.W.; Tang, Y.; Chen, S.; Zhou, Y.; Chen, J. -R.; Bagwill, C. Macrocyclic antibiotics as a new class of chiral selector for liquid chromatography,Anal. Chem. 1994,66, 1473–1484.

    Article  CAS  Google Scholar 

  35. Carpenter, J.L.; Camilleri, P.; Dhanak, D.; Goodall, D. A study of the binding of vancomycin to dipeptides using capillary electrophoresis,J. Chem. Soc. Chem. Commun. 1992, 804–806.

  36. Liu, J.; Volk, K.J.; Lee, M.S.; Pucci, M.; Handwerger, S. Binding Studies of Vancomycin to the Cytoplasmic Peptidoglycan Precursors by Affinity Capillary Electrophoresis,Anal. Chem. 1994,66, 2412–2416.

    Article  CAS  Google Scholar 

  37. Vespalec, R.; Corstjens, H.; Billiet, H.A.H.; Frank, J.; Luyben, K.Ch.A.M. Enantiomeric Separation of Sulfur- and Selenium-Containing Amino Acids by Capillary Electrophoresis Using Vancomycin as a Chiral Selector,Anal. Chem. 1995,67, 3223–3228.

    Article  CAS  Google Scholar 

  38. Rundlett, K.L.; Armstrong, D.W. Effect of Micelles and Mixed Micelles on Efficiency and Selectivity of Antibiotic-Based Capillary Electrophoretic Enantioseparations,Anal. Chem. 1995,67, 2088–2095.

    Article  CAS  Google Scholar 

  39. Fanali, S.; Desiderio, C.; Aturki, Z. Enantiomeric resolution study by capillary electrophoresis Selection of the appropriate chiral selector,J. Chromatogr. A 1997,772, 185–194.

    Article  CAS  Google Scholar 

  40. Fanali, S.; Desiderio, C.; Schulte, G.; Heitmeier, S.; Strickman, D.; Chankvetadze, B.; Blaschke, G. Chiral capillary electrophoresis-electrospray mass spectrometry coupling using vancomycin as chiral selector,J. Chromatogr. A 1998,800, 69–76.

    Article  CAS  Google Scholar 

  41. Reilly, J.; Risley, D.S. The Separation of Enantiomers by Countercurrent CE Using the Macrocyclic Antibiotic A82846B,LC-GC International September,1998, 598–606.

  42. Armstrong, D.W.; Gasper, M.P.; Rundlett, K.L. Highly enantioselective capillary electrophoretic separations with dilute solutions of the macrocyclic antibiotic ristocetin A,J. Chromatogr. A 1995,689, 285–304.

    Article  CAS  Google Scholar 

  43. Gasper, M.P.; Berthod, A.; Nair, U.B.; Armstrong, D.W. Comparison and Modeling Study of Vancomycin, Ristocetin A, Teicoplanin for CE Enantioseparations,Anal. Chem. 1996,68, 2501–2514.

    Article  CAS  Google Scholar 

  44. Carotti, A.; Di Gioia, F.; Cellamare, S.; Fanali, S. Teicoplanin-Based Enantiomeric Separations in CZE Using a Partial Filling Technique,J. High Resol. Chromatogr. 1999,22, 315–321.

    Article  CAS  Google Scholar 

  45. Wan, H.; Blomberg, L.G. Chiral separation of DL-peptides and enantioselective interactions between teicoplanin and D-peptides in capillary electrophoresis,Electrophoresis 1997,18, 943–949.

    Article  CAS  Google Scholar 

  46. D'Hulst, A.; Verbeke, N. Chiral separation by capillary electrophoresis with oligosaccharides,J. Chromatogr. 1992,608, 275–287.

    Article  Google Scholar 

  47. Chankvetadze, B.; Saito, M.; Yashima, E.; Okamoto, Y. Enantioseparation using selected polysaccharides as chiral buffer additives in capillary electrophoresis,J. Chromatogr. A 1997,773, 331–338.

    Article  CAS  Google Scholar 

  48. Bowser, M.T.; Kranack, A.R.; Chen, D.D.Y. Analyte-additive interactions in non-aqueous capillary electrophoresis: a critical review,TRAC 1998,17, 424–434.

    CAS  Google Scholar 

  49. Wang, F.; Khaledi, M.G. Chiral separations by Nonaqueous Capillary Electrophoresis,Anal. Chem. 1996,68, 3460–3467.

    Article  CAS  Google Scholar 

  50. Wang, F.; Khaledi, M.G., Nonaqueous capillary electrophoresis chiral separations with quaternary ammonium β-cyclodextrin,J. Chromatogr. A 1998,817, 121–128.

    Article  CAS  Google Scholar 

  51. Vincent, J.B.; Vigh, G. Nonaqueous capillary electrophoretic separation of enantiomers using the single-isomer heptakis(2,3-diacetyl-6-sulfato)-β-cyclodextrin as chiral resolving agent,J. Chromatogr. A 1998,816, 233–241.

    Article  CAS  Google Scholar 

  52. Bjrnsdottir, I.; Hansen, S.H.; Terabe, S. Chiral separation in non-aqueous media by capillary electrophoresis using the ion-pair principle,J. Chromatogr. A 1996,745, 37–44.

    Article  Google Scholar 

  53. Karbaum, A.; Jira, T. Chiral separation of unmodified amino acids with non-aqueous capillary electrophoresis based on the ligand-exchange principle,J. Chromatogr. A 2000,874, 285–292.

    Article  CAS  Google Scholar 

  54. Mardones, C.; Ríos, A.; Valcárcel, M.; Cicciarelli, R Enantiomeric separation of D- and L-carnitine by integrating on-line derivatisation with capillary electrophoresis,J. Chromatogr. A 1999,849, 609–616.

    Article  CAS  Google Scholar 

  55. Thorsén, G.; Engström, A.; Josefsson, B. Enantiomeric determination of amino componds with high sensitivity using the chiral reagents (+)- and (−)-1-(9-anthryl)-2-propyl chloroformate,J. Chromatogr. A 1997,786, 347–354.

    Article  Google Scholar 

  56. Liu, Y. -M.; Schneider, M.; Sticha, C.M.; Toyooka, T.; Sweedler, J.V. Separation of amino acid and peptide stereoisomers by nonionic micelle-mediated capillary electrophoresis after chiral derivatisation,J. Chromatogr. A 1998,800, 345–354.

    Article  CAS  Google Scholar 

  57. Jorgenson, J.W.; Lukacs, K.D. High-resolution separations, based upon electrophoresis and electroosmosis,J. Chromatogr. 1981,218, 209–216.

    Article  CAS  Google Scholar 

  58. Neue, U.D.. HPLC Columns Theory, Technology, Practice,Wiley-VCH New York,1997.

    Google Scholar 

  59. Knox, J.H.; Grant, I.H. Electrochromatography in Packed Tubes Using 1.5 to 50 μm Silica and ODS Bonded Silica Gels,Chromatographia 1991,32, 317–328.

    Article  CAS  Google Scholar 

  60. Adam, Th.; Lüdtke, S.; Unger, K.K. Packing and Stationary Phase Design for Capillary Electroendosmotic Chromatography (CEC),Chromatographia 1999,49, 49–55.

    Article  Google Scholar 

  61. Wen, E.; Asiaie, R.; Horváth, Cs. Dynamics of capillary electrochromatography II. Comparison of column efficiency parameters in microscale high-performance liquid chromatography and capillary electrochromatography,J. Chromatogr. A 1999,855, 349–366.

    Article  CAS  Google Scholar 

  62. Li, S.; Lloyd, D.K. Direct Chiral Separations by Capillary Electrophoresis Using Capillaries Packed with α1-Acid Glycoprotein Chiral Stationary Phase,Anal. Chem. 1993,65, 3684–3690.

    Article  CAS  Google Scholar 

  63. Carter-Finch, A.S.; Smith, N.W. Enantiomeric separations by capillary electrochromatography using a macrocyclic antibiotic chiral stationary phase,J. Chromatogr. A 1999,848, 375–385.

    Article  CAS  Google Scholar 

  64. Wolf, C.; Spence, P.L.; Pirkle, W.H.; Derrico, E.M.; Cavender, D.M.; Rozing, G.P. Enantioseparations by electrochromatography with packed capillaries,J. Chromatogr. A 1997,782, 175–179.

    Article  CAS  Google Scholar 

  65. Lämmerhofer, M.; Lindner, W., High-efficiency chiral separations of N-derivatized amino acids by packed-capillary electrochromatography with a quinine-based chiral anion-exchange type stationary phase,J. Chromatogr. A 1998,829, 115–125.

    Article  Google Scholar 

  66. Guttman, A.; Paulus, A.; Cohen, A.S.; Grinberg, N.; Karger, B.L. Use of complexing agents for selective separation in high-performance capillary electrophoresis. Chiral resolution via cyclodextrins incorporated within polyacrylamide gel columns,J. Chromatogr. 1988,448, 41–53.

    Article  CAS  Google Scholar 

  67. Koide, T.; Ueno, K. Enantiomeric Separations of Acidic and Neutral Compounds by Capillary Electrochromatography with β-Cyclodextrin-Bonded Positively Charged Polyacrylamide Gels,J. High Resol. Chromatogr. 2000,23, 59–66.

    Article  CAS  Google Scholar 

  68. Nilsson, S.; Schweitz, L.; Petersson, M. Three approaches to enantiomer separation of β-adrenergic antagonists by capillary electrochromatography,Electrophoresis 1997,18, 884–890.

    Article  CAS  Google Scholar 

  69. Mayer, S.; Schurig, V. Enantiomer Separation by Electrochromatography on Capillaries Coated With Chiralsil-Dex.J. High Resol. Chromatogr. 1992,15, 129–131.

    Article  CAS  Google Scholar 

  70. Mayer, S.; Schurig, V. Enantiomer separation by electrochromatography in open tubular columns coated with Chirasil-Dex,J. Liq. Chromatogr. 1993,16, 915–931.

    CAS  Google Scholar 

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Other chiral selectors. Chromatographia 54 (Suppl 1), S78–S92 (2001). https://doi.org/10.1007/BF02492895

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