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Stabilization of gas chromatographic stationary phases with nanosized particles

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Summary

Stabilization of polar and apolar stationary phases with nanosized particles has been demonstrated for gas chromatographic capillary columns. Mixtures of small amounts of (2–10%) of solid particles and liquids form gels, which preserve the stability of the films of stationary phases on the column walls. The stabilization effect of polar and apolar particles has been studied by determining some rheological properties of gels (flow curves, temperature dependence of yield stress values) and validated by gas chromatographic measurements using the most polar and apolar stationary phases.

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Authors and Affiliations

  1. Department of Physical Chemistry, Budapest University of Technology and Economics, 1521, Budapest, Hungary

    G. Tolnai & Z. Hórvölgyi

  2. Research Laboratory for Inorganic Chemistry, Hungarian Academy of Sciences, 1025, Pusztaszeri út 68, Budapest, Hungary

    G. Alexander

  3. Water Resources Research Centre Plc, H-1095, Kvassay J. út 1, Budapest, Hungary

    Z. Juvancz

  4. Department of Physical Chemistry, University of Veszprém, 8200, Veszprém, Hungary

    A. Dallos

Authors
  1. G. Tolnai
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  2. G. Alexander
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  3. Z. Hórvölgyi
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  4. Z. Juvancz
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  5. A. Dallos
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Additional information

Dedicated to the memory of late Dr. Gábor Alexander, who was the inventor of this film stabilization method, and took active part in the early experiments.

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Tolnai, G., Alexander, G., Hórvölgyi, Z. et al. Stabilization of gas chromatographic stationary phases with nanosized particles. Chromatographia 53, 69–75 (2001). https://doi.org/10.1007/BF02492430

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  • DOI: https://doi.org/10.1007/BF02492430

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