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Determination of aromatic sulfonates in coastal water by on-line Ion-pair solid-phase extraction/ion-pair liquid chromatography with UV detection

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Summary

A method for determining aromatic sulfonates in sea water is presented. Ion-pair solid phase extraction is coupled on-line to ion-pair liquid chromatography with UV detection. In the enrichment step, the recoveries from 100 mL of sea water were higher than 65% for most analytes. Linearity was good and detection limits were between 0.02 and 1 μgL−1. The repeatability of the method, expressed as % of relative standard deviation (n=3) was between 1 and 15%. The method was checked in coastal water near the commercial port of Tarragona, where effluents from the petrochemical industry are discharged. All the samples taken were found to contain 2-naphthalenesulfonate.

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Authors and Affiliations

  1. Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Imperial Tarraco 1, 43005, Tarragona, Spain

    R. A. Gimeno, R. M. Marcé & F. Borrull

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  1. R. A. Gimeno
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  2. R. M. Marcé
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  3. F. Borrull
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Gimeno, R.A., Marcé, R.M. & Borrull, F. Determination of aromatic sulfonates in coastal water by on-line Ion-pair solid-phase extraction/ion-pair liquid chromatography with UV detection. Chromatographia 53, 22–26 (2001). https://doi.org/10.1007/BF02492422

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  • DOI: https://doi.org/10.1007/BF02492422

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