Summary
A silica gel-bound, imprinted polymer for selective recognition of the diquat herbicide: 5,6-dihydropyrazino [1,2,3,4-lmn]-1,10-phenanthrolinium dichloride, is reported. It was used in the solid-phase extraction procedure, following liquid chromatography-differential pulse, adsorptive-stripping voltammetric (LC-DPAdSV) technique. The operational conditions for 100% retention of the diquat herbicide on a chromatographic column (13.0×1.4 cm, adsorbent bed 1.0g) were realized at pH 6.9 and a flow rate of 5.0 mL min−1. The adsorbent used could be regenerated during elution with 5.0 mL MHCl within 20 min. The limit of detection was 0.65 nM (0.18 ppb) with an enrichment factor as high as 99-fold.
Similar content being viewed by others
References
Pichon, V.; Chen, L.; Hennion, M.C.; Daniel, R.; Martel, A.; LeGoffic, F.; Abian, J.; Barcelo, D.Anal. Chem. 1995,67, 2451–2460.
Ferrer, I.; Lanza, F.; Tolokan, A.; Horvath, V.; Sellergren, B.; Horvai, G.; Barcelo, D.Anal. Chem. 2000,72, 3934–3941.
Bjarnason, B.; Chimuka, L.; Ramstrom, O.Anal. Chem. 1999,71, 2152–2156.
Kaiser, G.G.; Anderson, J.T.Fresenius J. Anal. Chem. 1992,342 (10), 834–838.
Knutsson, M.; Nilve, G.; Mathiasson, L.; Jonsson, J.A.J. Chromatographia A 1996,754, 197–205.
Lawrence, J.F.; Menard, C.; Hennion, M.C.; Pichon, V.; LeGoffic, F.; Durand, N.J. Chromatographia A 1996,752, 147–154.
Pichon, V.; Chen, L.; Durand, N.; LeGoffic, F.; Hennion, M.C.J. Chromatogr. A,1996,725, 107–119.
Land, C.C.J.LC-GC Int. 1994,7, 215–218.
(a) Wulff G. In polymeric Reagents and Catalysts, Ford, W.T. Ed.,A C S Symposium Series 308, American Chemical Society: Washington, DC,1986. (b) Wulff, G.; Vespor, W.; Grobo-Einsier, R.; Sarhan, A.Makromol. Chem. 1977,178, 2799. (c) Shea, K.J.; Dougherty, T.K.J. Am. Chem. Soc. 1986,108, 1091. (d) Wulff, G.; Heide, B.; Helfmeier, G.J. Am. Chem. Soc. 1986,108, 1089. (e) Andersson, L.; Sellergren, B.; Mosbach, K.Tetrahedron Lett. 1984,25, 5211.
Sellergren, B.; Lepisto, M.; Mosabach, K.J. Am. Chem. Soc. 1988,110, 5853, (b) Lepisto, M.; Sellergren, B.J. Org. Chem. 1989,54, 6010. (c) Sellergren, B.Chirality 1989,1, 63. (d) Andersson, L.I.; Mosbach, K.J. Chromatogr. 1990,516, 313. (e) Fischer, L.; Miller, R.; Ekberg, B.; Andersson, L.I.; Mosbach, K.J. Am. Chem. Soc. 1991,113, 9358–9360.
Sellergren, B.; Shea, K.J.J. Chromatogr. 1993,635, 31–49.
Shea, K.J.; Spivak, D.A.; Sellergren, B.J. Am. Chem. Soc. 1993,115, 3368–3369.
Vlatakis, G.; Andersson, L.I.; Miller, R.; Mosbach, K.Nature 1993,361, 645–647.
Wulff, G.ACS Symp. Ser. 1986, No.308, 186–230.
Shea, K.J.Trends Polym. Sci. 1994,2, 166–173.
Mosbach, K.Trends Biochem. Sci. 1994,19, 9–14.
Remcho, V.T.; Jessica, Z.Tan. Anal. Chem. News and Features,1999, 248–254.
Chen, Y.; Kele, M.; Saponz, P.; Sellergren, B.; Guichon, G.Anal. Chem. 1999,71, 928.
Vidyasankar, S.; Ru, M.; Arnol, F.H.J. Chromatogr., A,1997,775, 51.
Prasad, B.B.; Sundd, S.Bull. Chem. Soc. Jpn.,1995,68, 1–7.
Bruggermann, O.; Freitag, R.; Whitcombe, M.J.; Vufson, E.N.J. Chromatogr., A,1997,781, 43–53.
Dickeson, J.E.; Summers, L.A.J. Sci. Fd. Agric. 1969,20, 74.
Bellamy, C.J. “Advances in Infrared Frequencies”, Chaucer Press, Great Britain1968, p. 279.
Rochester, C.H.; Yong, G.H.J. Chem. Soc., Faraday Trans. 1 1980,76, 2142.
Okada, T.Anal. Chem. 1998,70, 1692–1700.
Kriz, D.; Ramström, O.; Mosbach, K.Anal. Chem.,1997,69, 345A.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Prasad, B.B., Banerjee, S. Determination of diquat herbicide by selective enrichment by column chromatography on imprinted polymer immobilised on silica gel. Chromatographia 55, 171–176 (2002). https://doi.org/10.1007/BF02492138
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02492138