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Evaluation of capillary gas chromatography columns for the determination of free volatile amines after solid-phase microextraction

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Summary

Gas-liquid chromatographic capillary columns coated with 14% diphenyldimethylpolysiloxane, base-deactivated 5% diphenyldimethylpolysiloxane, or poly(ethylene glycol), and deactivated porous polymer for capillary gas-solid chromatography were evaluated for analysis of low-molecular-weight (C1−C9) amines. Solid-phase microextraction with a polydimethylsiloxane fiber was used for headspace sampling and for introduction of the sample into the gas chromatograph. As expected, basic of aliphatic gaseous or volatile aliphatic amines (carbon number: C1−C4). A thick (e. g. 3 μm) film of 5% diphenyldimethylpolysiloxane enabled determination of analytes in a wider molecular-weight range (C3−C9) with acceptable efficiency and resolution.

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References

  1. Terashi, A.; Hanada, Y.; Kido, A.; Shinohara, R.J. Chromatogr. 1990,503, 369.

    Article  CAS  Google Scholar 

  2. Hoshika, Y.J. Chromatogr. 1975,115, 596.

    Article  CAS  Google Scholar 

  3. Pfundstein, B.; Tricker, A.R.; Pressmann, R.J. Chromatogr. 1991,539, 141.

    Article  CAS  Google Scholar 

  4. Da Costa, K.A.; Vrbanac, J.J.; Zeisel, S.H.Anal. Biochem. 1990,187, 234.

    Article  Google Scholar 

  5. Kataoka, H.J. Chromatogr. A1996,733, 19.

    Article  CAS  Google Scholar 

  6. Scully, F.E.; Howell, G.D.; Penn, H.H.; Mazina, K.; Johnson, J.D.Environ. Sci. Technol. 1988,22, 1186.

    Article  CAS  Google Scholar 

  7. Sacher, F.; Lenz, S.; Brauch, H.J.J. Chromatogr. A 1997,764, 85.

    Article  CAS  Google Scholar 

  8. Di Corcia, A.; Samperi, R.Anal. Chem. 1974,46, 977.

    Article  Google Scholar 

  9. Di Corcia, A.; Samperi, R.J. Chromatogr. 1973,77, 277.

    Article  Google Scholar 

  10. Smith, J.R.L.; Waddington, D.J.Anal. Chem. 1968,40, 522.

    Article  Google Scholar 

  11. Abdul-Rashid, M.K.; Riley, J.P.; Fitzsimons, M.F.; Wolf, G.A.Anal. Chim. Acta 1991,252, 223.

    Article  CAS  Google Scholar 

  12. Gronberg, L.; Lovkvist, P.; Jonsson, J.A.Chromatographia 1992,33, 77.

    Article  Google Scholar 

  13. Kuwata, K.; Akiyama, E.; Yamazaki, Y.; Yamasaki, H.; Kuge, Y.; Kiso, Y.Anal. Chem. 1983,55, 2199.

    Article  CAS  Google Scholar 

  14. Chriswell, C.D.; Fritz, J.S.J. Chromatogr. 1977,136, 371.

    Article  CAS  Google Scholar 

  15. Yang, X.H.; Lee, C.; Scranton, M.I.Anal. Chem. 1993,65, 572.

    Article  CAS  Google Scholar 

  16. Zhang, A.Q.; Mitchell, S.C.; Ayesh, R.; Smith, R.L.J. Chromatogr. 1992,584, 141.

    CAS  Google Scholar 

  17. Sidisky, L.M.; Kiefer, K.H.; Eksteen, R. Supelco,1996.

  18. Tsukioka, T.; Ozawa, H.; Murakami, T.J. Chromatogr. 1993,642, 395.

    Article  CAS  Google Scholar 

  19. Mohnke, M.; Schmidt, B.; Schmidt, R.; Buijten, J.C.; Mussche, Ph.J. Chromatogr. A 1994,667, 334.

    Article  CAS  Google Scholar 

  20. Ábalos, M.; Ventura, F.; Bayona, J.M.Anal. Chem. 1999,71, 3531.

    Article  Google Scholar 

  21. Budavari, S.; O'Neil, M.J.; Smith, A.; Heckelman, P.E.The Merck Index, 11th edn, Merck, Rahway, NY,1989.

    Google Scholar 

  22. Lyman, W.J.; Reehl, W.F.; Rosenblatt, D.H.Handbook of Chemical Property Estimation Methods, ACS, Washington, DC,1990.

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Authors and Affiliations

  1. Environmental Chemistry Department IIQAB-CSIC, Jordi Girona 18-26, 08034, Barcelona, Spain

    M. Ábalos, R. Mas & J. M. Bayona

  2. Teknokroma, Sant Cugat del Vallès, Barcelona, Spain

    V. Suc

Authors
  1. M. Ábalos
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  2. R. Mas
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  3. V. Suc
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  4. J. M. Bayona
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Ábalos, M., Mas, R., Suc, V. et al. Evaluation of capillary gas chromatography columns for the determination of free volatile amines after solid-phase microextraction. Chromatographia 54, 109–113 (2001). https://doi.org/10.1007/BF02491842

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  • DOI: https://doi.org/10.1007/BF02491842

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