Summary
A method for direct analysis of tepraloxydim and its main metabolites in water has been established by solid-phase extraction and HPLC-UV determination. It is demonstrated that chlorine added to disinfect tap water eliminates any possible residual tepraloxydim. Therefore, only the analytical method for determination of oxazol and imine metabolites of tepraloxydim has been validated to an LOQ of 0.1 μg·L−1, required by the Drinking Water Directive. This method has been validated following the most recent guidelines released by the European Commission on residue analytical methods.
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References
Framework Water Directive 2000/60/EC. Commission of the European Communities. Brussels,2000.
Drinking Water Directive 98/83/EC. Commission of the European Communities. Brussels,1998.
Drinking Water Directive 80/778/EEC. Commission of the European Communities. Brussels,1980.
Incledon, B.J.; Hall, J.C.Pestic. Biochem. and Physiol. 1997,57, 255–271.
Lichtenthaler, H.K.Z. Naturforsh 1990,45c, 521–528.
Rendina, A.R.; Felts, J.M.Plant Physiol. 1988,86, 983–986.
Kibler, E.; Landes, M.; Heyde, J. Von der; Jahn, D.; Munguer, PBri. Crop Prot. Conf.-Weeds 1999,1, 59–64.
Puig, D.; Barceló, D.Trends Anal. Chem. 1996,15, 362–375.
Hennion, M.C.Trends Anal. Chem. 1991,10, 317–323.
Font, G.; Mañes, J.; Moltó, J.C.; Picó, Y.J. Chromatogr. A 1993,642, 135–161.
Hu, J-Y.; Aizawa, T.; Magara, Y.Water Res. 1999,33, 417–425.
Johnson, W.E.; Fendinger, N.J.; Plimmer, J.R.Anal. Chem. 1991,63, 1510–1513.
Rojas, E. Personnal Communication. Madrid Municipal Laboratory.
Masqué, N.; Galià, M.; Marcé, R.M.; Borrull, F.J. Chromatogr. A 1998,803, 147–155.
Masqué, N.; Marcé, R.M.; Borrull, F.J. Chromatogr. A 1998,793, 257–263.
Fairhead, A.P.J. JWEM 1994,8, 399–401.
Zambonin, C.G.; Losito, I.; Palmisano, F.Rapid Commun. Mass Spectrom. 2000,14, 824–828.
Sancho-Llopis, J.V.Anal. Chim. Acta 1993,283, 287–296.
Guidance Document on Residue Analytical Methods. European Commission. Directorate General Health and Costumer Protection. SANCO/825/00 rev. 6. Brussels,2000.
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Sandín-España, P., González-Blázquez, J.J., Magrans, J.O. et al. Determination of herbicide tepraloxydim and main metabolites in drinking water by solid-phase extraction and liquid chromatography with UV detection. Chromatographia 55, 681–686 (2002). https://doi.org/10.1007/BF02491782
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DOI: https://doi.org/10.1007/BF02491782