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New method to determine LSER parameters

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  • Column Liquid Chromatography
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Summary

New method was developed to determining ∑β H2 andπ H2 descriptors of the linear solvation energy relationship (LSER) with micelle-water partition coefficient obtained using micellar liquid chromatography (MLC). This method was tested with chromatographic data of 20 organic compounds. Good results obtained confirm the validity of the method that opens new possibilities of precise and reliable determination of LSER descriptors of high boiling compounds. This method was used to establish ∑β H2 andπ H2 descriptors of 23 polyaromatic hydrocarbons that were not available in the literature.

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Authors and Affiliations

  1. Laboratoire de Thermodynamique des Milieux Polyphasés, ENSIC. INPL, 1 rue Grandville, BP 451, 54001, Nancy Cedex, France

    F. Mutelet

  2. Faculté de Chimie, USTHB, Bab-Ezzouar, BP 32 El-Alia, Alger, Algérie

    M. H. Guermouche

  3. Laboratoire de Thermodynamique des Milieux Polyphasés, Université de Metz, Ile du Saulcy, 57045, Metz, France

    M. Rogalski

Authors
  1. F. Mutelet
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  2. M. H. Guermouche
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  3. M. Rogalski
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Mutelet, F., Guermouche, M.H. & Rogalski, M. New method to determine LSER parameters. Chromatographia 57, 729–733 (2003). https://doi.org/10.1007/BF02491758

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  • DOI: https://doi.org/10.1007/BF02491758

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