Summary
The work is an overview of the methodology of investigation of volatile compounds evolved from plastics by headspace analysis. Polystyrene plastics and Chemosil lacquer were tested. The investigations were conducted at different temperatures and at different ratios of the surface area of the tested materials to the gas phase volume. Styrene, ethylbenzene and n-butyl alcohol were determined. Results of the calculations are listed in the tables and shown in the figures. On the basis of a mass balance the surface concentrations of the tested substances and their distribution coefficients between the solid and gas phases were also determined. The agreement between measured and calculated concentrations of the tested substances was very good.
Similar content being viewed by others
References
Trzeszczyński, J.Badania nad zanieczyszczeniem powietrza substancjami toksycznymi wydzielajacymi sie z tworzyw sztucznych (Investigations on Air Pollution by Toxic Substances Evolved from Plastics)—scientific dissertation, Technical University of Szczecin Press, Szczecin,1978.
Trzeszczyński, J.; Kukula, P.Chem. Anal. (Warsaw) 1989,34, 441–448.
Zimmermann, H. InDevelopments in Polymer Degradation, Vol. 5: Grassie, N., Ed., Applied Science Publishers, London,1984.
Skowronski, T.A.; Rabek, J.F.; R»nby, B.Polymer 1983,24, 1189–1196.
Schnabel, W.Polymer Degradation. Principles and Practical Applications, Carl Hanser Verlag, München-Wien,1981.
Varner, S.L.; Breder, C.V.; Fazio, T.J. Assoc. Off. Anal. Chem. 1983,66, 1067–1073.
Petersen, J.H.; Naamansen, E.T.Z. Lebensm. Unters. Forsch. A 1998,206, 156–160.
Gilbert, J.; Startin, J. R.J. Sci. Food Agric. 1983,34, 647–652.
Drozd, J.; Novák, J.J. Chromatogr. 1979,165, 141–165.
Ettre, L.S.; Kolb, B.Chromatographia 1991,32, 5–12.
Bachhausen, P.; Bucholz, N.; Hartkamp, H.Fresenius Z. Anal. Chem. 1985,322, 336–342.
Roblins, G.A.; Wang, S.; Stuart, J.D.Anal. Chem. 1993,65, 3113–3118.
Penton, Z.J. High Resol. Chromatogr. 1992,15, 834–836.
Hino, T.; Nakanishi, S.; Hobo, T.J. Chromatogr. 1996,746, 83–90.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Trzeszczyński, J., Huzar, E. Investigation of volatile compounds evolved from plastics by the headspace method. Chromatographia 53, 534–538 (2001). https://doi.org/10.1007/BF02491618
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02491618