Summary
The liquid-chromatographic separation of the enantiomers of pyrethroic acids and their esters has been investigated on a polysaccharide-derived chiral stationary phase (CSP), Chiralpak AS. Good separation of the enantiomers of underivatized pyrethroic acids was achieved on the column, and the enantiomers of pyrethroic acid methyl and ethyl ester derivatives were also resolved.
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References
Allenmark, S.G.Chromatographic Enantioseparation, Methods and Applications, 2nd edn, Ellis Horwood, Chichester,1991.
Krstulovic, A.M., Ed.,Chiral Separations by HPLC: Applications to Pharmaceutical Compounds, John Wiley and Sons, New York,1989.
Smith, C.Pyrethroid pesticides—the Market (DS 61). PJB Publications, UK,1992.
Smith, C.Pyrethroid Pesticides—Product Profiles (DS 59), PJB Publications, UK,1991, Section 1.
Davies, J.H. InThe Pyrethroid Insectivides: Leafy, J.P., Ed., Taylor and Francis, London, UK,1985, pp. 1–41.
Au, N.; Nagase, M.; Ina, Y.; Do, T.J. Chromatogr. 1983,263, 111–116.
Oi, N.; Nagase, M.; Inda, Y.; Doi, T.J. Chromatogr. 1983,259, 487–493.
Mitsuda, S.; Komaki, R.; Hirohara, H.; Nabeshima, S.Agric. Biol. Chem. 1991,55, 2865–2870.
Nishizawa, M.; Gomi, H.; Kishimoto, F.Biosci. Biotech. Biochem. 1993,57, 594–598.
Nishizawa, M.; Shimizu, M.; Ohkawa, H.; Kanaoka, M.Appl. Environ. Microbiol. 1995,61, 3208–3215.
Sinibaldi, M.; Flieger, M.; Cvak, L.; Messina, A.; Pichini, A.J. Chromatogr. A 1994,666, 471–478.
Oi, N.; Kitahara, H.; Aoki, F. Kisu, N.J. Chromatogr. A 1995,689, 195–201.
Oi, N.; Kitahara, H.; Matsushita, Y.; Kisu, N.J. Chromatogr. A 1996,722, 229–232.
Lee, W.; Kim, B.J. High Resol. Chromatogr. 1998,21, 189–192.
Kim, B.; Lee, W.Bull. Kor. Chem. Soc. 1998,19, 289–290.
Lee, W.Chromatographia 1999,49, 61–64.
Lee, W.Anal. Lett. 2000,33, 347–356.
Perry, J.A.; Rateike, J.D.; Szczerba, T.J.J. Chromatogr. 1987,389, 57–64.
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Lee, W. Separation of the enantiomers of pyrethroic acids and their esters by high-performance liquid chromatography on a polysaccharide-derived chiral stationary phase. Chromatographia 53, 156–158 (2000). https://doi.org/10.1007/BF02491563
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DOI: https://doi.org/10.1007/BF02491563