, Volume 52, Issue 3–4, pp 200–204 | Cite as

Cyclodextrin dimer derivatives used as stationary phase for capillary gas chromatography

  • X. Y. Shi
  • Y. Q. Zhang
  • J. H. Han
  • R. N. Fu
Originals Gas Chromatography


Four cyclodetrin dimer derivatives were synthesized by linking two single cyclodextrin derivatives with difunctional spacer at the primary side of cyclodetrin. The separation properties of these cylodextrin dimer derivatives as CGC stationary phases were investigated and compared with those of the unbridged native cyclodextrin derivative. The results show that two recognition sites and one link spacer of these cyclodextrin dimer derivatives cooperate in separation and affect the separation of disubstituted benzene positional isomers.

Key Words

Gas chromatography Cyclodextrin dimer stationary phases 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. [1]
    Schmalzing, D.; Martin, J.; Schurig, V.HRC 1992,15, 723.Google Scholar
  2. [2]
    Nowotny, H.P.; Schurig, V.J. Chromatogr. 1988,441, 155.CrossRefGoogle Scholar
  3. [3]
    Breslow, R.; Chung, S.J. Am. Chem. Soc. 1990,112, 9659.CrossRefGoogle Scholar
  4. [4]
    Breslow, R.; Halfon, S.; Zhang, B.Tetrahedron 1995,51, 377.CrossRefGoogle Scholar
  5. [5]
    Fokke, V.; Chantal, M.B.; Erik, V. D.; Bianca, H.M.R.Tetrahedron Letters 1994,35, 1773.CrossRefGoogle Scholar
  6. [6]
    Cramer, F.; Mackensen, G.; Sensse, K.Chem Ber. 1969,102,494 508.Google Scholar
  7. [7]
    Melton, L. D.; Slessor, K. N.Carbohydrate Research 1971,18, 23.CrossRefGoogle Scholar
  8. [8]
    Keim, W.; Kohnes, A.; Meltzow, W.HRC 1991,14, 507.Google Scholar
  9. [9]
    Schomburg, G.; Deege, A.; Hinrichs, H.HRC 1992,15, 579.Google Scholar
  10. [10]
    Tanaka, M.; Kowaguchi, Y.; Niinae, T.J. Chromatogr. 1984,314, 193.CrossRefGoogle Scholar
  11. [11]
    Hargitai, T.; Kaida, Y.; Okamoto, Y.J. Chromatogr. 1993,628, 11.CrossRefGoogle Scholar
  12. [12]
    Takeuchi, T.; Toriyama, H.; Shimura, S.; Takayama, Y.HRC 1995,18, 179.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 2000

Authors and Affiliations

  • X. Y. Shi
    • 1
  • Y. Q. Zhang
    • 1
  • J. H. Han
    • 1
  • R. N. Fu
    • 1
  1. 1.School of Chemical Engineering and Materials ScienceBeijing Institute of TechnologyBeijingP.R. China

Personalised recommendations