Abstract
Acoustophoresis has been used to study the evolution of the surface potential of hydrating cement suspensions because it is potentially capable of measuring zeta potentials of cement suspensions at concentrations high enough not to modify ion/particle interactions, which is not the case for most other methods. Measurements were performed using cement with and without addition of high-range water reducing admixture (HRWRA). In this paper it will be shown that quantitative determination of the potential is rendered difficult by the large size of cement particles as well as by ongoing hydration reactions. Other benefits of the technique will be discussed.
Résumé
L'acoustophorèse a été utilisée pour étudier l'évolution du potentiel de surface de suspensions de pâtes de ciment, durant leur hydratation, parce que cette technique est potentiellement capable de mesurer le potentiel zêta d'une suspension de ciment à des concentrations suffisamment élevées pour ne pas modifier les interactions ion/particule, ce qui n'est pas le cas de la plupart des autres méthodes. Les mesures ont été faites, en présence ou non d'adjuvants à pouvoir réducteur d'eau élevé. Dans cet article, on démontre aussi que la détermination quantitative du potentiel est rendue difficile à cause de la large taille des particules ainsi que des réactions d'hydratation. D'autres avantages de cette technique sont également discutés.
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References
Mehta, P. K., ‘Role of pozzolanic and cementitious material in sustainable development of the concrete industry’, Proc. 6th Canmet/ACI Int. Conf. Fly-Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, (American Concrete Institute, Detroit, SP-178, 1998) 1–20.
Edmeades, R. M. and Hewlett, P. C., ‘Cement Admixtures’, in ‘Lea's Chemistry of Cement and Concrete’, (Armold, London, 1988) 837–901.
Ramachandran, V. S., Ramachandran, V. S. and Vasundhara, S., ‘Admixtures Formulations’, in ‘Concrete Admixtures Handbook, Properties, Science, and Technology’, (1995) 1045–1076.
Fernon, V., Vichot, A., Le Goanvic, N., Colombet, P., Corazza, F. and Costa, U., ‘Interaction between Portland cement hydrates and polynaphtalene sulfonates’, Proc. 5th Canmet/ACI Int. Conf. on superplasticizers and Other Chemical Admixtures in Concrete. (ACI Detroit, SP-173, 1997) 225–248.
Flatt, R., and Houst, Y. F., ‘A simplified view on chemical effects perturbing the action of superplasticizers’,Cem. Concr. Res. (accepted) (2001).
Funk, J. E. and Dinger, D. R., ‘Predictive Process Control of Crowded Particulate Suspensions; Applied to Ceramic Manufacturing’, (Kluwer Academic Publishers, Norwell USA, 1994).
Nägele, E., ‘The zeta-potential of cement’,Cem. Concr. Res. 15 (1985) 453–462.
Nägele, E., ‘The zeta-potential of cement. Part II: Effect of pH-value’,Cem. Concr. Res. 16 (1986) 853–863.
Uchikawa, H., Hanehara, S. and Sawaki, D., ‘The role of steric repulsive force in the dispersion of cement particles in fresh paste prepared with organic admixtures’,Cem. Concr. Res. 27 (1) (1997) 37–50.
Darwin, D. C., Leung, R. Y. and Taylor, T., ‘Surface characterisation of Portland cement in presence of superplasticizers’, Proc. of Workshop held at the National Institute of Technology, February 3–4, (Gaithersburg, USA, 1993) NIST Special Publication 856.
Nachbaur, L., ‘Etude de l'influence d'électrolytes sur l'hydratation et la prise du silicate tricalcique, composant principal, du ciment Portland. Caractérisation des interactions à l'origine de la prie’, PhD. Thesis (Université de Bourgognd, France, 1997) 141p.
O'Brien, W. O., ‘Electron-acoustic effects in a dilute suspension of spherical particles’,J. Fluid. Mech. 190 (1988) 71–80.
James, M., Hunter, R. J. and O'Brien, W. O., ‘Effect of particle size distribution and aggregation on electroacoustic measurement of ξ potential’,Langmuir (1992) 420–423.
Marlow, B. J., Fairhurst, D. and Pendse, H. P., ‘Colloid vibration potential and the electrokinetic characterization of concentrated colloids’,Langmuir 4 (1988) 611–626.
Ferraris, C. and de Larrard, F., ‘Testing and modelling of fresh concrete rheology’, National Institute of Standards and Technology, NISTIR 6094 (1997).
Hackley, V. A. and Malghan, S. G., ‘Investigation of parameters and secondary components affecting the electroacoustic analysis of silicon nitride powders’ in ‘Electroacoustics for Characterization of Particulates and Suspensions’, NIST Special Publication 856, (USDoC, Technology Administration, Gaithersburg, USA, 1993) 161–179.
Damidot, D., Sorrentino, D. and Guinot, D., ‘Factors influencing the nucleation and growth of the hydrates in cementitious systems: an experimental approach, 2nd Int. RILEM Symposium, ‘Why does cement set, An interdisciplinary approach’ (RILEM PRO 13, Rilem Publications, Cachan, 2000) 161–197,
Enderby, J. A., ‘On electrical effects due to sound waves in colloidal suspensions’, Proc. of the Royal Society, Series A, Mathematical and Physical Sciences, No. 1088, 207 (1951) 329–342.
Temkin, S., ‘Sphere in a sound wave’, § 6.10 in ‘Elements of Acoustics’, (John Wiley & Sons, New York, 1981).
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Editorial Note Dr. Chiara F. Ferraris is a RILEM Senior Member and works at NIST, a RILEM Titular Member, The Swiss Federal Institute of Technology (EPFL) is a RILEM Titular Member.
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Flatt, R.J., Ferraris, C.F. Acoustophoretic characterization of cement suspensions. Mat. Struct. 35, 541–549 (2002). https://doi.org/10.1007/BF02483122
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DOI: https://doi.org/10.1007/BF02483122