Materials and Structures

, Volume 32, Issue 3, pp 224–229 | Cite as

Molecular weight distribution of regular asphalts from dynamic material functions

  • L. Zanzotto
  • J. Stastna
  • S. Ho
Scientific Reports

Abstract

Dynamic material functions are among the most sensitive tools for determining the molecular weight distribution of rheologically complex systems. The phase angle of the complex modulus especially is sensitive to the molecular weight of the studied material; it can therefore be used as the input to the inverse problem of determining the molecular weight from this important dynamic material function. Molecular weight distributions of several regular asphalts are calculated using the phase angle and compared with molecular weight distribution obtained by gel permeation chromatography. The problems of calculating molecular weight distributions from rheological parameters are also discussed.

Keywords

Asphalt Phase Angle Molecular Weight Distribution Complex Modulus Master Curf 

Résumé

Les fonctions de matériau dynamique sont parmi les outils les plus sensibles pour déterminer la distribution de masse moléculaire des systèmes rhéologiques complexes. L'angle de phase du module complexe est spécialement sensible à la masse moléculaire du matériau étudié; il peut donc être utilisé comme donnée d'entrée pour le problème inverse afin de déterminer la masse moléculaire à partir de cette importante fonction de matériau dynamique. Les distributions de masse moléculaire de plusieurs asphaltes réguliers sont calculées en utilisant cet angle de phase et ensuite comparées avec la distribution de masse moléculaire obtenue par chromatographie sur gel perméable. Les problèmes de calcul des distributions de masse moléculaire à partir de paramètres rhéologiques sont aussi discutés.

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Copyright information

© RILEM 1999

Authors and Affiliations

  • L. Zanzotto
    • 1
  • J. Stastna
    • 1
  • S. Ho
    • 1
  1. 1.Faculty of EngineeringThe University of CalgaryCalgaryCanada

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