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Kinetics of dimethyldioxirane decomposition in the presence of cumene

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Abstract

Dimethyldioxirane consumption increases considerably in the presence of cumene. The product composition (cumic alcohol, acetophenone, α-methylstyrene) and the inhibiting effect of oxygen prove a radical reaction mechanism. The kinetic order for dimethyldioxirane increases with the conversion from 1.5 to 2.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, prospekt Oktyabrya 71, 450054, Ufa, Russia

    D. V. Kazakov, N. N. Kabalnova, S. L. Khursan, S. A. Grabovsky & V. V. Shereshovets

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  1. D. V. Kazakov
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  2. N. N. Kabalnova
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  3. S. L. Khursan
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  4. S. A. Grabovsky
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  5. V. V. Shereshovets
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Kazakov, D.V., Kabalnova, N.N., Khursan, S.L. et al. Kinetics of dimethyldioxirane decomposition in the presence of cumene. React Kinet Catal Lett 60, 131–135 (1997). https://doi.org/10.1007/BF02477701

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  • DOI: https://doi.org/10.1007/BF02477701

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