Contributions to quantum biology. I. Mobile electronic characteristics of riboflavin radicals
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Quantum biology is the quantum mechanical study of electrons in molecules of biological interest. This requires the solution of problems involving many electrons. Approximation methods are therefore necessary and are discussed. The present study, concerned with the mobile electrons in riboflavin (FMN) and its radicals (FMN−, FMNH and FMNH2 +), is based on the approximation method, developed by B. Pullman and A. Pullman. The solution of the eigenvalue problems so obtained gives the energy levels of the mobile electron systems involved. The corresponding eigenvectors yield the mobile electronic charges of the atoms of riboflavin radicals which have contributed mobile electrons. Important differences of the net charge distributions of these radicals are emphasized. The longest wave length of light absorption is calculated from the obtained energy levels and agrees, within the accuracy of the method, with corresponding experimental results. From the appropriate calculated results, electronic assignments are obtained for the experimental transitions involved.
KeywordsRiboflavin Atom Number Mobile Electron Weak Acid Solution Quantum Mechanical Study
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- Coulson, C. A. 1952.Valence. Oxford: Clarendon Press.Google Scholar
- Fajans, K. 1949. “Electric Forces and Electronic Configurations in Carbon Compounds.”Chem. and Eng. News.,27, 900–04.Google Scholar
- — 1959. “Quantikel-Theorie der Chemischen Binding.”Chimia.,13, 349–66.Google Scholar
- Karreman, G., I. Isenberg and A. Szent-Györgyi. 1959. “On the Mechanism of Action of Chlorpromazine.”Science,130, 1191–92.Google Scholar
- Pitzer, K. S. 1953.Quantum Chemistry, New York: Prentice-Hall.Google Scholar
- Pauling, L. 1948.The Nature of the Chemical Bond. Ithaca: Cornell University Press.Google Scholar
- Pullman, A. and B. Pullman. 1952.Les Théories Electroniques de la Chimie Organique. Paris: Masson et Cie.Google Scholar
- Pullman, A. and B. Pullman. 1955.Cancérisation par les Substances Chimiques et Structure Moléculaire. Paris: Masson et Cie.Google Scholar
- Pullman, B. and A. Pullman. 1958a. “La Chimiothérapie des Cancers et des Leucémies.” Comp. Rend. Centre National de la Recherche Scientifique. Colloques Internat. 3 et 4 mai 1957, 201–14.Google Scholar
- Szent-Györgyi, A. 1960.Introduction to a Submolecular Biology. New York: Acad. Press.Google Scholar