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Partial oxidation of ethane in H2/O2 fuel cell under mild conditions

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Abstract

The partial oxidation of ethane to ethanol and acetaldehyde in the H2/O2 fuel cell under mild conditions is reported. The reaction proceeds at the carbon gasdiffusion cathode in the presence of transition metal ions (Fe2+, Cu2+) at ambient pressure and temperature 343 K.

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References

  1. K. Otsuka, M. Kunieda, H. Yamagata:J. Electrochem. Soc.,139, 2381 (1992).

    Article  CAS  Google Scholar 

  2. I. Yamanaka, K. Otsuka:J. Chem. Soc. Faraday Trans.,89, 1791 (1993).

    Article  CAS  Google Scholar 

  3. K. Otsuka, K. Ishizuka, I. Yamanaka:Chem. Lett., 773 (1992).

  4. I. Yamanaka, K. Otsuka:J. Chem. Soc. Faraday Trans.,90, 451 (1994).

    Article  CAS  Google Scholar 

  5. R.L. Cook, A.F. Sammels:J. Electrochem. Soc.,137, 2007 (1990).

    Article  CAS  Google Scholar 

  6. K.W. Frese, Jr.:Langmuir,7, 13 (1991).

    Article  CAS  Google Scholar 

  7. K. Otsuka, K. Ishizuka, I. Yamanaka, M. Natano:J. Electrochem. Soc.,138, 3176 (1991).

    Article  CAS  Google Scholar 

  8. K. Otsuka, Y. Shimizu, I. Yamanaka:J. Electrochem. Soc.,137, 2076 (1990).

    Article  CAS  Google Scholar 

  9. A. Parmaliana, F. Frusteri, F. Arena, N. Giordano:Catal. Lett.,12, 353 (1992).

    Article  CAS  Google Scholar 

  10. A. Parmaliana:New Developments in Selective Oxidation, Vol. 55, p. 733. Elsevier Science Publishers B. V., Amsterdam, 1990.

    Google Scholar 

  11. F. Frusteri, E.N. Savinov, A. Parmaliana, E.R. Savinova, V.N. Parmon, N. Giordano:Catal. Lett.,27, 355 (1994).

    Article  CAS  Google Scholar 

  12. A.O. Kuzmin, E.R. Savinova, V.N. Parmon:React. Kinet. Catal. Lett.,66, 359 (1998).

    Google Scholar 

  13. Q. Zhang, K. Otsuka:Chem. Lett., 363 (1997).

  14. A.O. Kuzmin, E.R. Savinova, F. Frusteri, A. Parmaliana, V.N. Parmon:Proc. EUROPACAT II, Maastricht, the Netherlands, 550, 1995.

  15. F. Frusteri, A. Parmaliana, V. Sokolovskii, N. Giordano:1st European Congress on Catalysis, Montpellier 1993.

  16. D. Dobos:Electrochemical data. Akad. Kiadó, Budapest 1978.

    Google Scholar 

  17. J. Weiss:Advances in Catalysis and Related Subjects, Vol. IV, Eds. W.G. Frankenburg and V.I. Komarewsky, 1952.

  18. J. Baxendale:Advances in Catalysis and Related Subjects, Vol. IV, Eds. W.G. Frankenburg and V.I. Komarewsky, 1952.

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Kuzmin, A.O., Savinova, E.R. & Parmon, V.N. Partial oxidation of ethane in H2/O2 fuel cell under mild conditions. React Kinet Catal Lett 66, 351–357 (1999). https://doi.org/10.1007/BF02475812

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