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On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions

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Abstract

The rate-limiting stage of heterogeneous catalytic redox reactions with participation of strongly bound surface species, such as nitrates, carbonates and sulfites, is the interaction of these heteroatomic oxidants with the reducing agents. It appears to be mainly determined by their bonding strength with the surface, being independent of the nature of the central atom (carbon, sulfur, nitrogen) and the energy of its bond with oxygen.

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References

  1. A.Ya. Rozovskii, G.I. Lin:Theoretical Basis of the Methanol Synthesis Process, Khimiya, Moscow 1990 (in Russian).

    Google Scholar 

  2. V.A. Sadykov, E.A. Paukshtis, S.A. Beloshapkin, G.M. Alikina, S.A. Veniaminov, E.V. Netyaga, R.V. Bunina, E.V. Lunina, A.N. Kharlanov, V.V. Lunin, V.A. Matyshak, A.Ya. Rozovskii:React. Kinet. Catal. Lett.,65, 113 (1998).

    CAS  Google Scholar 

  3. V.A. Sadykov, S.A. Beloshapkin, E.A. Paukshtis, G.M. Alikina, D.I. Kochubei, S.P. Degtyarev, N.N. Bulgakov, S.A. Veniaminov, E.V. Netyaga, R.V. Bunina, A.N. Kharlanov, E.V. Lunina, V.V. Lunin, V.A. Matyshak, A.Ya. Rozovskii:React. Kinet. Catal. Lett.,64, 185 (1998).

    CAS  Google Scholar 

  4. V.A. Sadykov, S.L. Baron, V.A. Matyshak, G.M. Alikina, R.V. Bunina, A.Ya. Rozovskii, V.V. Lunin, E.V. Lunina, A.N. Kharlanov, A.S. Ivanova, S.A. Veniaminov:Catal. Lett.,37, 157 (1996).

    Article  CAS  Google Scholar 

  5. V.I. Marshneva, K.A. Dubkov, V.V. Mokrinskii, E.A. Paukshtis, A.A. Davydov:Kinet. Catal.,31, 1199 (1990).

    CAS  Google Scholar 

  6. A.V. Deo, I.G. Dalla Lana, H.W. Habgood:J. Catal.,21, 270 (1971).

    Article  CAS  Google Scholar 

  7. P.H. Berben, M.J. Kappers, J.W. Geus:Mikrochim. Acta,II, 15 (1988).

    Article  Google Scholar 

  8. V.I. Marshneva, V.V. Mokrinskii:Kinet. Catal.,29, 989 (1988).

    CAS  Google Scholar 

  9. A. Datta, R.G. Cavell:J. Phys. Chem.,89, 454 (1985).

    Article  CAS  Google Scholar 

  10. D.A. Abaskuliev, Yu.F. Vysheslavtsev, N.M. Guseinov:Conditioning and Processing of Gas and Gas Condensate, Ser. Rev.,11, 1 (1988).

    Google Scholar 

  11. H.A. El Masry:Appl. Catal.,3, 301 (1985).

    Google Scholar 

  12. P.E. Mc Gregor: Ph. D. Thesis, University of Alberta, Canada 1971.

  13. Ch.C. Chang:J. Catal.,53, 374 (1978).

    Article  CAS  Google Scholar 

  14. K.P. Mischenko, A.A. Ravdel, Eds.:Brief Reference Book of Physicochemical Parameters. Khimiya, Leningrad 1972 (in Russian).

    Google Scholar 

  15. A.D. Cowan, R. Dumpelmann, N.W. Cant:J. Catal.,151, 356 (1995).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    V. A. Sadykov, G. M. Alikina, G. A. Buchtiyarova & B. P. Zolotovskii

  2. Topchiev Institute of Petrochemical Synthesis RAS, Moscow, Russia

    A. Ya. Rozovskii & G. I. Lin

  3. Chemical Department, Lomonosov Moscow State University, Moscow, Russia

    V. V. Lunin

  4. Department of Natural Sciences, Novisibirsk State University, Novosibirsk, Russia

    S. A. Beloshapkin

Authors
  1. V. A. Sadykov
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  2. A. Ya. Rozovskii
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  3. V. V. Lunin
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  4. G. I. Lin
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  5. G. M. Alikina
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  6. G. A. Buchtiyarova
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  7. B. P. Zolotovskii
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  8. S. A. Beloshapkin
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Sadykov, V.A., Rozovskii, A.Y., Lunin, V.V. et al. On the nature of factors determining reactivity of strongly bound surface species as intermediates in heterogeneous catalytic redox reactions. React Kinet Catal Lett 66, 337–341 (1999). https://doi.org/10.1007/BF02475810

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  • DOI: https://doi.org/10.1007/BF02475810

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