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Oxidation of methyl phenyl sulfide with molecular oxygen in the presence of isobutyraldehyde and transition metal monosubstituted heteropolytungstates

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Abstract

Methyl phenyl sulfide is quantitatively oxidized to the corresponding sulfoxide and sulfone by dioxygen in the presence of isobutyraldehyde and transition metal substituted heteropolytungstates, PW11MO39 n- (M=CoII, and TiIV). The reaction proceedsvia a radical chain mechanism.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    I. V. Khavrutskii, G. M. Maksimov & O. A. Kholdeeva

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  1. I. V. Khavrutskii
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  2. G. M. Maksimov
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  3. O. A. Kholdeeva
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Khavrutskii, I.V., Maksimov, G.M. & Kholdeeva, O.A. Oxidation of methyl phenyl sulfide with molecular oxygen in the presence of isobutyraldehyde and transition metal monosubstituted heteropolytungstates. React Kinet Catal Lett 66, 325–330 (1999). https://doi.org/10.1007/BF02475808

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  • DOI: https://doi.org/10.1007/BF02475808

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