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IR studies of the transformations of nitrogen-containing organic intermediates during selective reduction of nitrogen oxides by hydrocarbons

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Abstract

Thermal transformations of nitromethane and deuterated acetonitrile adsorbed on the surface of H-ZSM-5, Cu-ZSM-5, Co-ZSM-5 has been studied by IR spectroscopy. The nature of cation has been found to greatly affect the transformation pathways of these species as possible intermediates in the NOx selective reduction by hydrocarbons, thus explaining the different selectivities of these catalysts.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis SB RAS, 630090, Novosibirsk, Russia

    S. A. Beloshapkin, E. A. Paukshtis & V. A. Sadykov

  2. Semenov Institute of Chemical Physics RAS, Moscow, Russia

    V. A. Matyshak, A. N. Ilyichev & A. A. Ukharskii

  3. Chemical Department of Lomonosov Moscow State University, Moscow, Russia

    V. V. Lunin

Authors
  1. S. A. Beloshapkin
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  2. V. A. Matyshak
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  3. E. A. Paukshtis
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  4. V. A. Sadykov
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  5. A. N. Ilyichev
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  6. A. A. Ukharskii
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  7. V. V. Lunin
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Beloshapkin, S.A., Matyshak, V.A., Paukshtis, E.A. et al. IR studies of the transformations of nitrogen-containing organic intermediates during selective reduction of nitrogen oxides by hydrocarbons. React Kinet Catal Lett 66, 297–304 (1999). https://doi.org/10.1007/BF02475804

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  • DOI: https://doi.org/10.1007/BF02475804

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