Advertisement

Reaction Kinetics and Catalysis Letters

, Volume 66, Issue 2, pp 281–287 | Cite as

Styrene oligomerization in the presence of catalytic systems based on Pd(acac)2 and BF3OEt2

  • V. S. Tkach
  • G. Myagmarsuren
  • M. Mesyef
  • F. K. Shmidt
Article

Abstract

Styrene oligomerization in the presence of Pd(acac)2+PPh3+BF3OEt2 catalytic system (acac—acetylacetonate) has been studied. Styrene conversion at optimum conditons (T=343 K, B/Pd=7, P/Pd=2) was as high as 75,000 mol of C3H3 per mol of Pd in 7 h with a selectivity to dimers, mostly 1,3-diphenylbut-1-ene, up to 93%.

Keywords

Palladium styrene oligomerization 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    V.S. Tkach, F.K. Shmidt, N.A. Murasheva, N.D. Malakhova, T.V. Dmitrieva, G.V. Ratovskii:React. Kinet. Catal. Lett.,36, 213 (1988).CrossRefGoogle Scholar
  2. 2.
    V.S. Tkach, F.K. Shmidt, G.V. Ratovskii, N.D. Malakhova, N.A. Murasheva, M.L. Chernyshev, O.V. Burlakova:React. Kinet. Catal. Lett.,36, 257 (1988).CrossRefGoogle Scholar
  3. 3.
    V.S. Tkach:D.Sc. Thesis, ISU, Irkutsk 1991.Google Scholar
  4. 4.
    M.L. Chernyshev, V.S. Tkach, T.V. Dmitrieva, G.V. Ratovskii, S.V. Zinchenko, F.K. Shmidt:Kinet. Catal.,38, 575 (1997).Google Scholar
  5. 5.
    V.S. Tkach, F.K. Shmidt, T.V. Dmitrieva, G.V. Ratovskii, N.D. Malakhova, N.A. Murasheva, G. Myagmarsuren:Russ. J. Coord. Chem.,14, 1424 (1988).Google Scholar
  6. 6.
    V.S. Tkach, G. Myagmarsuren, T.V. Dmitrieva, G.V. Ratovskii, F.K. Shmidt:Symp. Org. Chem., Saint-Peterburg,:Zh. Org. Khim., 170 (1995).Google Scholar
  7. 7.
    M.L. Chernyshev, V.S. Tkach, T.V. Dmitrieva, G.V. Ratovskii, S.V. Zinchenko, F.K. Shmidt:React. Kinet. Catal. Lett.,48, 291 (1992).CrossRefGoogle Scholar
  8. 8.
    T.V. Dmitrieva, G.V. Ratovskii, N.D. Malakhova, V.S. Tkach, F.K. Shmidt:Russ. J. Coord. Chem.,21, 933 (1995).Google Scholar
  9. 9.
    G. Henrici-Olive, S. Olive:Coordination and Catalysis, 421 p., Verlag Chemie, New-York, Weinheim 1977.Google Scholar
  10. 10.
    I.I. Moiseev:Itogi Nauki i Tekhniki. Kinetika i kataliz,13, p. 147, VINITI, Moscow 1984 (in Russian).Google Scholar
  11. 11.
    G. Myagmarsuren:Ph.D. Thesis, ISU, Irkutsk 1993.Google Scholar
  12. 12.
    G.V. Ratovskii, O.V. Tyukalova, V.S. Tkach, F.K. Shmidt:Zh. Obshch. Khim.,66, 1791 (1996).Google Scholar

Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • V. S. Tkach
    • 1
  • G. Myagmarsuren
    • 1
  • M. Mesyef
    • 1
  • F. K. Shmidt
    • 1
  1. 1.Irkutsk State UniversityIrkutskRussia

Personalised recommendations